C₆₃H₇₇N₃

Base Information

• Chemical Name: C₆₃H₇₇N₃
• CAS No.: 1309964-64-4
• Molecular Formula: C₆₃H₇₇N₃
• Molecular Weight: 876.324
• Mol file: 1309964-64-4.mol

Synonyms:C₆₃H₇₇N₃

Chemical Property of C₆₃H₇₇N₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₃H₇₇N₃

There total 4 articles about C₆₃H₇₇N₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

3,5-Di-tert-butylbenzaldehyde (17610-00-3) + 4,4',4''-tridiethylmethylphosphonate-2,2':6',2''-terpyridine (1309964-63-3) → C63H77N3 (1309964-64-4)

Guidance literature:

4,4',4''-tridiethylmethylphosphonate-2,2':6',2''-terpyridine; With sodium hydride; In tetrahydrofuran; at 20 ℃; for 0.5h;

3,5-Di-tert-butylbenzaldehyde; In tetrahydrofuran; for 12h; Reflux;

DOI:10.1039/c0dt01417f

Reference yield:

trimethyl 2,2:6′,2''-terpyridine-4,4',4''-tricarboxylate (330680-46-1) → C63H77N3 (1309964-64-4)

Guidance literature:

Multi-step reaction with 4 steps

1.1: sodium tetrahydroborate / ethanol / 4 h / Reflux

2.1: sulfuric acid; hydrogen bromide / water / 6 h / Reflux

2.2: pH 7

3.1: chloroform / 6 h / Inert atmosphere; Reflux

4.1: sodium hydride / tetrahydrofuran / 0.5 h / 20 °C

4.2: 12 h / Reflux

With sodium tetrahydroborate; sulfuric acid; hydrogen bromide; sodium hydride; In tetrahydrofuran; ethanol; chloroform; water;

DOI:10.1039/c0dt01417f

Reference yield:

4,4',4''-trihydroxymethyl-2,2':6',2''-tripyridine (1309964-61-1) → C63H77N3 (1309964-64-4)

Guidance literature:

Multi-step reaction with 3 steps

1.1: sulfuric acid; hydrogen bromide / water / 6 h / Reflux

1.2: pH 7

2.1: chloroform / 6 h / Inert atmosphere; Reflux

3.1: sodium hydride / tetrahydrofuran / 0.5 h / 20 °C

3.2: 12 h / Reflux

With sulfuric acid; hydrogen bromide; sodium hydride; In tetrahydrofuran; chloroform; water;

DOI:10.1039/c0dt01417f

upstream raw materials:

4,4',4''-tribromomethyl-2,2':6',2''terpyridine

4,4',4''-trihydroxymethyl-2,2':6',2''-tripyridine

3,5-Di-tert-butylbenzaldehyde

4,4',4''-tridiethylmethylphosphonate-2,2':6',2''-terpyridine