benzyl 2-acetamido-4,6-dichloro-2,4,6-trideoxy-3-O--α-D-galactopyranoside

Base Information

• Chemical Name: benzyl 2-acetamido-4,6-dichloro-2,4,6-trideoxy-3-O--α-D-galactopyranoside
• CAS No.: 40269-14-5
• Molecular Formula: C₁₉H₂₅Cl₂NO₆
• Molecular Weight: 434.317
• Mol file: 40269-14-5.mol

Synonyms:benzyl 2-acetamido-4,6-dichloro-2,4,6-trideoxy-3-O--α-D-galactopyranoside

Chemical Property of benzyl 2-acetamido-4,6-dichloro-2,4,6-trideoxy-3-O--α-D-galactopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of benzyl 2-acetamido-4,6-dichloro-2,4,6-trideoxy-3-O--α-D-galactopyranoside

There total 2 articles about benzyl 2-acetamido-4,6-dichloro-2,4,6-trideoxy-3-O--α-D-galactopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

benzyl 2-acetamido-2-deoxy-3-O--α-D-glucopyranoside (19229-59-5,24909-47-5,39523-95-0,39524-06-6,40269-09-8) → benzyl 2-acetamido-4,6-dichloro-2,4,6-trideoxy-3-O--α-D-galactopyranoside (40269-14-5)

Guidance literature:

With tetrachloromethane; triphenylphosphine; at 80 ℃; for 3h;

DOI:10.1016/S0008-6215(00)85983-2

Reference yield:

→ 2-((2S,3R,4R,5R,6R)-3-Acetylamino-2-benzyloxy-5-chloro-6-chloromethyl-tetrahydro-pyran-4-yloxy)-propionic acid methyl ester (40269-14-5)

Guidance literature:

Glucopyranosid 1, SO2Cl2/Pyridin;

DOI:10.1246/bcsj.45.3611

Reference yield: 91.0%

benzyl 2-acetamido-4,6-dichloro-2,4,6-trideoxy-3-O--α-D-galactopyranoside (40269-14-5) → benzyl 2-acetamido-2,4,6-trideoxy-3-O--α-D-xylo-hexopyranoside (40269-15-6)

Guidance literature:

With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In toluene; for 18h; Heating;

DOI:10.1016/S0008-6215(00)85983-2

upstream raw materials:

benzyl 2-acetamido-2-deoxy-3-O--α-D-glucopyranoside

Downstream raw materials:

benzyl 2-acetamido-2,4,6-trideoxy-3-O--α-D-xylo-hexopyranoside

benzyl 2-acetamido-2,4,6-trideoxy-3-O-(D-2-propionyl-L-alanyl-D-isoglutamine benzyl ester)-α-D-xylo-hexopyranoside

benzyl 2-acetamido-4,6-dichloro-2,4,6-trideoxy-3-O-(D-2-propionyl-L-alanyl-D-isoglutamine benzyl ester)-α-D-galactopyranoside