5,10-dioxatricyclo[7.1.0.0^4,6]decane

Base Information

• Chemical Name: 5,10-dioxatricyclo[7.1.0.0^4,6]decane
• CAS No.: 19740-81-9
• Molecular Formula: C₈H₁₂O₂
• Molecular Weight: 140.182
• Mol file: 19740-81-9.mol

Synonyms:5,10-dioxatricyclo[7.1.0.0^4,6]decane

Chemical Property of 5,10-dioxatricyclo[7.1.0.0^4,6]decane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,10-dioxatricyclo[7.1.0.0^4,6]decane

There total 11 articles about 5,10-dioxatricyclo[7.1.0.0^4,6]decane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.3%

1,5-cis,cis-cyclooctadiene (1552-12-1,111-78-4) → 1,2:5,6-diepoxycyclooctane (286-75-9,19740-81-9,57378-35-5)

Guidance literature:

With phosphoric acid; sulfuric acid; dihydrogen peroxide; sodium tungstate; Aliquat 336; In water; 1,2-dichloro-ethane; at 70 ℃; for 1h; pH=1.6; microwave irradiation;

DOI:10.1080/00397910500278479

Reference yield: 98.0%

cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4) → 1,2:5,6-diepoxycyclooctane (286-75-9,19740-81-9,57378-35-5)

Guidance literature:

With 2,2,2-Trifluoroacetophenone; dihydrogen peroxide; In acetonitrile; tert-butyl alcohol; at 20 ℃; for 1h; Green chemistry;

DOI:10.1021/jo5003938

Reference yield: 86.7%

cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4) → 1,2:5,6-diepoxycyclooctane (286-75-9,19740-81-9,57378-35-5) + 5,6-epoxycyclooctene (73176-71-3,637-90-1,73176-86-0,1225194-35-3,1225194-65-9)

Guidance literature:

With C₃₀H₂₅ClCoN₃OP; dihydrogen peroxide; 1-ethyl-3-methylimidazolium hexafluorophosphate; In water; at 20 ℃; for 2h; Green chemistry;

DOI:10.1016/j.crci.2013.12.004

upstream raw materials:

1,5-cis,cis-cyclooctadiene

1,5-dimethyl-1,5-cyclooctadiene

cyclo-octa-1,5-diene

Downstream raw materials:

butanedinitrile

C₁₄H₁₉NO₂

C₁₅H₂₁NO₂

C₃₅H₄₅NO₈