ac-{(η5-C5H5)Re(NO)(PPh3)(CCHC6H5)}(CF3SO3)

Base Information

Chemical Name:ac-{(η5-C5H5)Re(NO)(PPh3)(CCHC6H5)}(CF3SO3)
CAS No.:82582-38-5
Molecular Formula:CF₃O₃S*C₃₁H₂₆NOPRe
Molecular Weight:794.805
Hs Code.:

Synonyms:ac-{(η5-C5H5)Re(NO)(PPh3)(CCHC6H5)}(CF3SO3)

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Chemical Property of ac-{(η5-C5H5)Re(NO)(PPh3)(CCHC6H5)}(CF3SO3)

Chemical Property:

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Technology Process of ac-{(η5-C5H5)Re(NO)(PPh3)(CCHC6H5)}(CF3SO3)

There total 3 articles about ac-{(η5-C5H5)Re(NO)(PPh3)(CCHC6H5)}(CF3SO3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 82582-45-4
(η5-C5H5)Re(NO)(PPh3)(CCC6H5)

: 1493-13-6
trifluorormethanesulfonic acid

: 82582-38-5
C₅H₅ReNOP(C₆H₅)3C₂HC₆H₅⁽¹⁺⁾*CF₃SO₃^(1-)=ReC₅H₅NOP(C₆H₅)3C₂HC₆H₅CF₃SO₃

: 82659-75-4
C₅H₅ReNOP(C₆H₅)3C₂HC₆H₅⁽¹⁺⁾*CF₃SO₃^(1-)=ReC₅H₅NOP(C₆H₅)3C₂HC₆H₅CF₃SO₃

Guidance literature:: In not given; Re-complex was reacted with ligand at -78.dgeree.C;
DOI:10.1021/ja00382a036

Reference yield:

: 82582-45-4
(η5-C5H5)Re(NO)(PPh3)(CCC6H5)

: 1493-13-6
trifluorormethanesulfonic acid

: 82659-75-4
sc-{(η5-C5H5)Re(NO)(PPh3)(CCHC6H5)}(CF3SO3)

: 82582-38-5
ac-{(η5-C5H5)Re(NO)(PPh3)(CCHC6H5)}(CF3SO3)

Guidance literature:: In dichloromethane-d2; addn. of CF3SO3H to soln. of CpRe(NO)(PPh3)(CCC6H5) in CD2Cl2 under nitrogen at -196°C in a NMR tube via syringe, warmed to -78°C;; detected by (1)H-NMR, ac-/sc-ratio >99:1, ac-/sc-ratio 20:80 after 24 h at 25°C;;
DOI:10.1021/ja00226a026

Reference yield:

: 82582-48-7
(η-C5H5)Re(NO)(PPh3)(COCH2C6H5)

: 358-23-6
trifluoromethylsulfonic anhydride

: 865-47-4
potassium tert-butylate

: 82582-38-5
C₅H₅ReNOP(C₆H₅)3C₂HC₆H₅⁽¹⁺⁾*CF₃SO₃^(1-)=ReC₅H₅NOP(C₆H₅)3C₂HC₆H₅CF₃SO₃

: 82659-75-4
C₅H₅ReNOP(C₆H₅)3C₂HC₆H₅⁽¹⁺⁾*CF₃SO₃^(1-)=ReC₅H₅NOP(C₆H₅)3C₂HC₆H₅CF₃SO₃

Guidance literature:: In not given; to Re-complex was added (CF3SO2)2O, then K-t-BuO was added, mixt. was treated with (CF3SO2)2 at -78°C;
DOI:10.1021/ja00382a036