trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)2SiMe₃

Base Information

Chemical Name:trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)2SiMe₃
CAS No.:945679-68-5
Molecular Formula:C₅₅H₆₅F₅P₂PtSi
Molecular Weight:1106.23
Hs Code.:

trans-(C<sub>6</sub>F<sub>5</sub>)(Ph<sub>2</sub>P)2(CH<sub>2</sub>)18Pt(C<sub>2</sub>)2SiMe<sub>3</sub>

Synonyms:trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)2SiMe₃

Suppliers and Price of trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)2SiMe₃

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)2SiMe₃

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)2SiMe₃

There total 2 articles about trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)2SiMe₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 647012-18-8
trans-PtCl(C₆F₅)(PPh₂(CH₂)18PPh₂)

: 72965-79-8
(trimethylsilyl)(trimethylstannyl)butadiyne

: 945679-68-5
trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)2SiMe₃

Guidance literature:: With KPF₆; copper(l) iodide; In methanol; dichloromethane; a Schlenk flask was charged with Pt-complex, (CH3)3SnC4Si(CH3)3, CuI, KPF6, CH2Cl2 and methanol with stirring, 16 h; the solvent was removed by oil pump vac.;
DOI:10.1021/ja071612n

Reference yield:

: 647012-10-0
trans-PtCl(C₆F₅)(PPh₂(CH₂)8CH=CH₂)2

: 945679-68-5
trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)2SiMe₃

Guidance literature:: Multi-step reaction with 2 steps

1: Pd/C / Grubbs catalyst first generation / not given

2: KPF₆ / copper(l) iodide / dichloromethane; methanol

With Pd/C; KPF₆; copper(l) iodide; Grubbs catalyst first generation; In methanol; dichloromethane;
DOI:10.1021/ja071612n

Reference yield: 84.0%

: 945679-68-5
trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)2SiMe₃

: 945679-59-4,945679-71-0
trans,trans-(C₆F₅)(Ph₂P)2(CH₂)18Pt(C₂)4Pt(CH₂)18(Ph₂P)2(C₆F₅)

Guidance literature:: With catalyst:CuCl/N,N,N',N'-tetramethylethylenediamine; (C₄H₉)4NF; O₂; In tetrahydrofuran; water; acetone; diamine was added to CuCl in acetone, stirred for 0.5 h, (n-C4H9)4NF in THF/5 wt%H2O was added to a soln. of Pt-complex in acetone with stirring, after 20 min (CH3)3SiCl was added, O2 was bubbled, heated to 65°C, Cu-soln. was added over 4 h, 0.5h;
DOI:10.1021/ja071612n