Cy₃PAu-CC-1,2-di(2-methylthien-3-yl)hexafluorocyclopentene-CC-AuPCy₃

Base Information

• Chemical Name: Cy₃PAu-CC-1,2-di(2-methylthien-3-yl)hexafluorocyclopentene-CC-AuPCy₃
• CAS No.: 1231960-36-3
• Molecular Formula: C₅₅H₇₄Au₂F₆P₂S₂
• Molecular Weight: 1369.2
• Mol file: 1231960-36-3.mol

Synonyms:Cy₃PAu-CC-1,2-di(2-methylthien-3-yl)hexafluorocyclopentene-CC-AuPCy₃

Chemical Property of Cy₃PAu-CC-1,2-di(2-methylthien-3-yl)hexafluorocyclopentene-CC-AuPCy₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cy₃PAu-CC-1,2-di(2-methylthien-3-yl)hexafluorocyclopentene-CC-AuPCy₃

There total 1 articles about Cy₃PAu-CC-1,2-di(2-methylthien-3-yl)hexafluorocyclopentene-CC-AuPCy₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

(tricyclohexylphosphine)gold(I) chloride (49763-41-9) + 3,3'-(3,3,4,4,5,5-hexafluoro-1-cyclopentene-1,2-diyl)bis[5-ethynyl-2-methylthiophene] (348639-20-3) → Cy3PAu-CC-1,2-di(2-methylthien-3-yl)hexafluorocyclopentene-CC-AuPCy3 (1231960-36-3)

Guidance literature:

With sodium hydroxide; In tetrahydrofuran; methanol; (N2) soln. diacetylene in MeOH was added to soln. Au complex in MeOH, stirred at room temp., soln. NaOH in MeOH was added dropwise, stirred for 2 h; ppt. was filtered, washed with MeOH, water and ether, dried in vacuo for2 h; elem. anal.;

DOI:10.1021/om1000919

Reference yield:

Cy3PAu-CC-1,2-di(2-methylthien-3-yl)hexafluorocyclopentene-CC-AuPCy3 (1231960-36-3) → C5F6(C4H(CH3)(CCAu(P(C6H11)3))S)2

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); irradiation with UV light (302 nm) or visible light (> 420 nm);

DOI:10.1021/om1000919

upstream raw materials:

(tricyclohexylphosphine)gold(I) chloride

3,3'-(3,3,4,4,5,5-hexafluoro-1-cyclopentene-1,2-diyl)bis[5-ethynyl-2-methylthiophene]