trichloro-[(2-phenyliminomethyl-6-tert-butyl)phenolato](tetrahydrofurane)titanium

Base Information

• Chemical Name: trichloro-[(2-phenyliminomethyl-6-tert-butyl)phenolato](tetrahydrofurane)titanium
• CAS No.: 639806-63-6
• Molecular Formula: C₂₁H₂₆Cl₃NO₂Ti
• Molecular Weight: 478.682

Synonyms:trichloro-[(2-phenyliminomethyl-6-tert-butyl)phenolato](tetrahydrofurane)titanium

Chemical Property of trichloro-[(2-phenyliminomethyl-6-tert-butyl)phenolato](tetrahydrofurane)titanium

Chemical Property:

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Technology Process of trichloro-[(2-phenyliminomethyl-6-tert-butyl)phenolato](tetrahydrofurane)titanium

There total 1 articles about trichloro-[(2-phenyliminomethyl-6-tert-butyl)phenolato](tetrahydrofurane)titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

tetrachlorobis(tetrahydrofuran)titanium(IV) (31011-57-1,112925-19-6,112925-18-5) + N-[(3-tert-butyl-2-trimethylsilyloxy)phenyl]methylene aniline (639806-66-9) → trichloro-[(2-phenyliminomethyl-6-tert-butyl)phenolato](tetrahydrofurane)titanium (639806-63-6)

Guidance literature:

In dichloromethane; (N2); a soln. of Ti complex treated with a soln. of ligand at -78°C, warmed slowly to room temp., stirred for 16 h; evapd. (vac.), washed (light petroleum), recrystd. (CH2Cl2/light petroleum/THF, -30°C); elem. anal.;

DOI:10.1039/b414229b

Reference yield: 62.0%

Ti[((CH3)3C)C6H3(O)CHN(C6H5)]Cl3(C4H8O) (639806-63-6) + potassium 4-phenylamino-3-penten-2-onate → TiCl2(OC6H3(C(CH3)3)CHNC6H5)(OC(CH3)CHC(CH3)NC6H5)

Guidance literature:

In dichloromethane; byproducts: KCl; under N2; soln. of Ti complex in CH2Cl2 at -78°C treated with K compd.; warmed slowly to room temp.; stirred for 16 h; filtered; filtrate concd.; cooled; elem. anal.;

DOI:10.1016/j.jorganchem.2006.03.026

Reference yield:

Ti[((CH3)3C)C6H3(O)CHN(C6H5)]Cl3(C4H8O) (639806-63-6) + K(pyrrole-2-phenylcarbaldimine(1-)) → Ti[((CH3)3C)C6H3(CHNC6H5)(O)][(C6H5NCH)C4H3N]Cl2

Guidance literature:

In dichloromethane; byproducts: KCl; cooled in dichloromethane/light petroleum solution to -25°C;

DOI:10.1039/b504113a

upstream raw materials:

tetrachlorobis(tetrahydrofuran)titanium(IV)

N-[(3-tert-butyl-2-trimethylsilyloxy)phenyl]methylene aniline

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