methyl (2S,3R)-2,3-dihydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate

Base Information

Chemical Name:methyl (2S,3R)-2,3-dihydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate
CAS No.:1228079-07-9
Molecular Formula:C₁₉H₃₂O₅Si
Molecular Weight:368.546
Hs Code.:

Synonyms:methyl (2S,3R)-2,3-dihydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (2S,3R)-2,3-dihydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate

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Technology Process of methyl (2S,3R)-2,3-dihydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate

There total 2 articles about methyl (2S,3R)-2,3-dihydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 1228078-90-7
methyl (2E)-3-{4'-[(triisopropylsilyl)oxy]phenyl}acrylate

: 1228079-07-9
methyl (2S,3R)-2,3-dihydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate

Guidance literature:: With K₃Fe(CN)6; methanesulfonamide; potassium osmate(VI) dihydrate; potassium carbonate; (9S,9"S)-9,9"-[phthalazine-1,4-diylbis-(oxy)]bis[10,11-dihydro-6'-methoxycinchonane]; In water; tert-butyl alcohol; at 0 - 20 ℃; optical yield given as %ee;
DOI:10.1002/chem.200903500

Reference yield:

: 1228078-90-7
methyl (2E)-3-{4'-[(triisopropylsilyl)oxy]phenyl}acrylate

: 1228078-91-8
methyl (2R,3S)-2,3-dihydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate

: 1228079-07-9
methyl (2S,3R)-2,3-dihydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate

Guidance literature:: With potassium osmate(VI) dihydrate; 4-methylmorpholine N-oxide; 4-[(R)-[(2R,4R,5S)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxy-4-quinolinyl)methoxy]-1-[(R)-[(2R,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl]-(6-methoxy-4-quinolinyl)methoxy]phthalazine; In water; tert-butyl alcohol; at 20 ℃; for 3h; optical yield given as %ee;
DOI:10.1002/chem.200903500

Reference yield: 47.0%

: 1228079-07-9
methyl (2S,3R)-2,3-dihydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate

: 1228079-08-0
methyl (2S,3S)-3-azido-2-hydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate

: 1228079-16-0
methyl (2S,3R)-3-azido-2-hydroxy-3-{4'-[(triisopropylsilyl)oxy]phenyl}propanoate

Guidance literature:: With hydrogen azide; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; toluene; at 0 - 20 ℃; for 18h; regioselective reaction;
DOI:10.1002/chem.200903500