(1E,1'E)-5-tert-butyl-3-(((4-(((5-tert-butyl-2-hydroxy-3-((E)-(hydroxyimino)methyl)benzyl)(methyl)amino)methyl)benzyl)(methyl)amino)methyl)-2-hydroxybenzaldehyde oxime

Base Information

• Chemical Name: (1E,1'E)-5-tert-butyl-3-(((4-(((5-tert-butyl-2-hydroxy-3-((E)-(hydroxyimino)methyl)benzyl)(methyl)amino)methyl)benzyl)(methyl)amino)methyl)-2-hydroxybenzaldehyde oxime
• CAS No.: 1350476-09-3
• Molecular Formula: C₃₄H₄₆N₄O₄
• Molecular Weight: 574.764
• Mol file: 1350476-09-3.mol

Synonyms:(1E,1'E)-5-tert-butyl-3-(((4-(((5-tert-butyl-2-hydroxy-3-((E)-(hydroxyimino)methyl)benzyl)(methyl)amino)methyl)benzyl)(methyl)amino)methyl)-2-hydroxybenzaldehyde oxime

Chemical Property of (1E,1'E)-5-tert-butyl-3-(((4-(((5-tert-butyl-2-hydroxy-3-((E)-(hydroxyimino)methyl)benzyl)(methyl)amino)methyl)benzyl)(methyl)amino)methyl)-2-hydroxybenzaldehyde oxime

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1E,1'E)-5-tert-butyl-3-(((4-(((5-tert-butyl-2-hydroxy-3-((E)-(hydroxyimino)methyl)benzyl)(methyl)amino)methyl)benzyl)(methyl)amino)methyl)-2-hydroxybenzaldehyde oxime

There total 4 articles about (1E,1'E)-5-tert-butyl-3-(((4-(((5-tert-butyl-2-hydroxy-3-((E)-(hydroxyimino)methyl)benzyl)(methyl)amino)methyl)benzyl)(methyl)amino)methyl)-2-hydroxybenzaldehyde oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

3,3'-(1,4-phenylenebis(methylene))bis(methylazanediyl)bis(methylene)bis(5-tert-butyl-2-hydroxybenzaldehyde) (1350476-08-2) → (1E,1'E)-5-tert-butyl-3-(((4-(((5-tert-butyl-2-hydroxy-3-((E)-(hydroxyimino)methyl)benzyl)(methyl)amino)methyl)benzyl)(methyl)amino)methyl)-2-hydroxybenzaldehyde oxime (1350476-09-3)

Guidance literature:

With hydroxylamine hydrochloride; potassium hydroxide; In ethanol; chloroform; at 20 ℃; for 15h;

DOI:10.1039/c1dt10808e

Reference yield:

N,N'-(p-Phenylenedimethylidyne)bis(methylamine) (41464-83-9) → (1E,1'E)-5-tert-butyl-3-(((4-(((5-tert-butyl-2-hydroxy-3-((E)-(hydroxyimino)methyl)benzyl)(methyl)amino)methyl)benzyl)(methyl)amino)methyl)-2-hydroxybenzaldehyde oxime (1350476-09-3)

Guidance literature:

Multi-step reaction with 3 steps

1: sodium tetrahydroborate / methanol / 1 h

2: triethylamine / methanol; dichloromethane / 15 h / 20 °C

3: hydroxylamine hydrochloride; potassium hydroxide / ethanol; chloroform / 15 h / 20 °C

With sodium tetrahydroborate; hydroxylamine hydrochloride; triethylamine; potassium hydroxide; In methanol; ethanol; dichloromethane; chloroform;

DOI:10.1039/c1dt10808e

Reference yield:

terephthalaldehyde, (623-27-8) → (1E,1'E)-5-tert-butyl-3-(((4-(((5-tert-butyl-2-hydroxy-3-((E)-(hydroxyimino)methyl)benzyl)(methyl)amino)methyl)benzyl)(methyl)amino)methyl)-2-hydroxybenzaldehyde oxime (1350476-09-3)

Guidance literature:

Multi-step reaction with 4 steps

1: potassium hydroxide / methanol / 3 h / 20 °C

2: sodium tetrahydroborate / methanol / 1 h

3: triethylamine / methanol; dichloromethane / 15 h / 20 °C

4: hydroxylamine hydrochloride; potassium hydroxide / ethanol; chloroform / 15 h / 20 °C

With sodium tetrahydroborate; hydroxylamine hydrochloride; triethylamine; potassium hydroxide; In methanol; ethanol; dichloromethane; chloroform;

DOI:10.1039/c1dt10808e

upstream raw materials:

3-(bromomethyl)-5-(tert-butyl)-2-hydroxybenzaldehyde

N,N'-dimethyl-p-xylylenediamine

3,3'-(1,4-phenylenebis(methylene))bis(methylazanediyl)bis(methylene)bis(5-tert-butyl-2-hydroxybenzaldehyde)

terephthalaldehyde,