(S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine

Base Information

• Chemical Name: (S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine
• CAS No.: 185449-81-4
• Molecular Formula: C₂₄H₂₀NO₃P
• Molecular Weight: 401.401
• Hs Code.: 2934999090
• DSSTox Substance ID: DTXSID50470890
• Nikkaji Number: J1.313.490A
• Wikidata: Q72472396
• Mol file: 185449-81-4.mol

Synonyms:185449-81-4;(S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine;636559-56-3;(11bR)-4-(4-Morpholinyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin;(S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]-dioxaphosphepin-4-yl)morpholine;4-(12,14-dioxa-13-phosphapentacyclo[13.8.0.02,11.03,8.018,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yl)morpholine;(S)-MORFPHOS;4-(12,14-dioxa-13-phosphapentacyclo[13.8.0.0^{2,11.0^{3,8.0^{18,23]tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-yl)morpholine;96% pound not99%ee;SCHEMBL15422409;4-(11bR)-Dinaphtho[2,1-d;DTXSID50470890;4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine;4-(11bR)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-ylmorpholine;SY223948;CS-0085218;CS-0086853;E78668;F52256;4-(4H-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine;(R)-4-(DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-YL)MORPHOLINE;(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a;3,4-a'']dinaphthalen-4-yl)morpholine;(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a 3,4-a']dinaphthalen-4-yl)morpholine;(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a;3,4-a']dinaphthalen-4-yl)morpholine, 97%;4-?(11bR)?-Dinaphtho[2,?1-?d:1',?2'-?f]?[1,?3,?2]?dioxaphosphepin-?4-?ylmorpholine;4-(11bR)-Dinaphtho[2 pound not1-d:1' pound not2'-f][1 pound not3 pound not2]dioxaphosphepin-4-ylmorpholine;4-(11bS)-Dinaphtho[2 pound not1-d:1' pound not2'-f][1 pound not3 pound not2]dioxaphosphepin-4-ylmorpholine;4-[(11bR)-Dinaphtho[2,1-d:1 inverted exclamation mark ,2 inverted exclamation mark -f][1,3,2]dioxaphosphepin-4-yl]morpholine

Chemical Property of (S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine

Chemical Property:

• Boiling Point: 613.7±65.0 °C(Predicted)
• PKA: -0.88±0.20(Predicted)
• PSA: 44.52000
• LogP: 5.92820
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: moisture sensitive
• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 401.11808050
• Heavy Atom Count: 29
• Complexity: 530

Purity/Quality:

99%, ^*data from raw suppliers

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)morpholine, min. 97% (S)-MorfPhos ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1COCCN1P2OC3=C(C4=CC=CC=C4C=C3)C5=C(O2)C=CC6=CC=CC=C65

Technology Process of (S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine

There total 1 articles about (S)-4-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)morpholine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

morpholine (110-91-8,99108-56-2) + binaphthol chlorophosphite (137156-22-0,171878-71-0,155613-52-8) → (S)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)morpholine (185449-81-4,636559-56-3,879083-10-0)

Guidance literature:

With base; In tetrahydrofuran; Combinatorial reaction / High throughput screening (HTS);

DOI:10.1021/om300194k

upstream raw materials:

morpholine

binaphthol chlorophosphite

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