tert-butyl 6-(dibenzylamino)-3,3-dimethyl-2,3-dihydro-1Hbenzo[d][1,3]azagermole-1-carboxylate

Base Information

Chemical Name:tert-butyl 6-(dibenzylamino)-3,3-dimethyl-2,3-dihydro-1Hbenzo[d][1,3]azagermole-1-carboxylate
CAS No.:1622407-01-5
Molecular Formula:C₂₉H₃₆GeN₂O₂
Molecular Weight:517.207
Hs Code.:

Synonyms:tert-butyl 6-(dibenzylamino)-3,3-dimethyl-2,3-dihydro-1Hbenzo[d][1,3]azagermole-1-carboxylate

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Chemical Property of tert-butyl 6-(dibenzylamino)-3,3-dimethyl-2,3-dihydro-1Hbenzo[d][1,3]azagermole-1-carboxylate

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Technology Process of tert-butyl 6-(dibenzylamino)-3,3-dimethyl-2,3-dihydro-1Hbenzo[d][1,3]azagermole-1-carboxylate

There total 11 articles about tert-butyl 6-(dibenzylamino)-3,3-dimethyl-2,3-dihydro-1Hbenzo[d][1,3]azagermole-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 1622406-91-0
tert-butyl(2-bromo-5-(dibenzylamino)phenyl)(((chloromethyl)dimethylgermyl)methyl)carbamate

: 1622407-01-5
tert-butyl 6-(dibenzylamino)-3,3-dimethyl-2,3-dihydro-1Hbenzo[d][1,3]azagermole-1-carboxylate

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; at -78 ℃; for 1h;
DOI:10.3987/COM-18-S(T)70

Reference yield: 76.0%

: 1622406-91-0
tert-butyl(2-bromo-5-(dibenzylamino)phenyl)(((chloromethyl)dimethylgermyl)methyl)carbamate

: 1622407-01-5
tert-butyl 6-(dibenzylamino)-3,3-dimethyl-2,3-dihydro-1Hbenzo[d][1,3]azagermole-1-carboxylate

: 1622407-26-4
C₂₈H₃₄GeN₂O₂

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; hexane; at -78 ℃; for 1h; regioselective reaction; Inert atmosphere;
DOI:10.1002/chem.201402597

Reference yield:

: 10403-47-1
2-bromo 5-nitroaniline

: 1622407-01-5
tert-butyl 6-(dibenzylamino)-3,3-dimethyl-2,3-dihydro-1Hbenzo[d][1,3]azagermole-1-carboxylate

Guidance literature:: Multi-step reaction with 6 steps

1: dmap / dichloromethane / 24 h / 20 °C

2: zinc; ammonium chloride / acetone / 4 h / Reflux

3: sodium iodide; potassium carbonate / N,N-dimethyl-formamide / 24 h / 20 °C

4: potassium carbonate / methanol / 4 h / 20 °C

5: sodium hydride / N,N-dimethyl-formamide / 3 h / 80 °C

6: tert.-butyl lithium / tetrahydrofuran / 1 h / -78 °C

With dmap; tert.-butyl lithium; sodium hydride; potassium carbonate; ammonium chloride; sodium iodide; zinc; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; acetone;
DOI:10.3987/COM-18-S(T)70