8-O-acetylgoniotriol

Base Information

• Chemical Name: 8-O-acetylgoniotriol
• CAS No.: 129578-08-1
• Molecular Formula: C₁₅H₁₆O₆
• Molecular Weight: 292.288
• Mol file: 129578-08-1.mol

Synonyms:8-O-acetylgoniotriol

Chemical Property of 8-O-acetylgoniotriol

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 8-O-acetylgoniotriol

There total 5 articles about 8-O-acetylgoniotriol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

7-O-Acetyl-4,6-O-isopropylidene-7-C-phenyl-D-gluco-hept-2-enono-δ-lactone → 8-O-acetylgoniotriol (129578-08-1)

Guidance literature:

In acetic acid; at 70 - 80 ℃; for 4h;

DOI:10.3987/rev-96-487

Reference yield: 77.0%

Acetic acid (1R,2R)-2-benzyloxy-2-((2R,3S)-3-hydroxy-6-oxo-3,6-dihydro-2H-pyran-2-yl)-1-phenyl-ethyl ester → 8-O-acetylgoniotriol (129578-08-1)

Guidance literature:

With titanium tetrachloride; In dichloromethane;

DOI:10.1021/jo970725u

Reference yield: 59.0%

(5S,6R,7R,8R)-6-<8-acetoxy-7,8-dihydro-7-(methoxymethoxy)styryl>-5-(methoxymethoxy)-5,6-dihydro-2H-pyran-2-one (153619-52-4) → 8-O-acetylgoniotriol (129578-08-1) + 8-epi-altholactone-7-O-acetate (153744-08-2)

Guidance literature:

With trifluoroacetic acid; In dichloromethane; for 1.5h; Ambient temperature;

DOI:10.1016/S0040-4020(99)00023-X

upstream raw materials:

(5S,6R,7R,8R)-6-<8-acetoxy-7,8-dihydro-7-(methoxymethoxy)styryl>-5-(methoxymethoxy)-5,6-dihydro-2H-pyran-2-one

(5S,6R)-5-hydroxy-6-<(1R,2R)-1,2-isopropylidenyloxy-2-phenylethyl>-5,6-dihydropyran-2-one

4,6-O-Isopropylidene-7-C-phenyl-D-gluco-hept-2-enono-δ-lactone

Downstream raw materials:

8-epi-altholactone-7-O-acetate