(5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-endo-hexahydro-1,4-methanonaphthalene)(η5-cyclopentadienyl)cobalt

Base Information

Chemical Name:(5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-endo-hexahydro-1,4-methanonaphthalene)(η5-cyclopentadienyl)cobalt
CAS No.:113567-75-2
Molecular Formula:C₄₀H₃₅Co
Molecular Weight:574.711
Hs Code.:

Synonyms:(5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-endo-hexahydro-1,4-methanonaphthalene)(η5-cyclopentadienyl)cobalt

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Chemical Property of (5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-endo-hexahydro-1,4-methanonaphthalene)(η5-cyclopentadienyl)cobalt

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Technology Process of (5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-endo-hexahydro-1,4-methanonaphthalene)(η5-cyclopentadienyl)cobalt

There total 4 articles about (5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-endo-hexahydro-1,4-methanonaphthalene)(η5-cyclopentadienyl)cobalt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 498-66-8
norborn-2-ene

: η5-cyclopentadienylbis(ethene)cobalt

: 501-65-5
diphenyl acetylene

: (η(5)-cyclopentadienyl)(.eta(4)-tetraphenylcyclobutadiene)cobalt(I)

: 113666-00-5
(5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-exo-hexahydro-1,4-methanonaphthalene)(η5-cyclopentadienyl)cobalt

: 113567-75-2
(5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-endo-hexahydro-1,4-methanonaphthalene)(η5-cyclopentadienyl)cobalt

Guidance literature:: In toluene; Under N2, addn. of diphenylacetylene to cooled (0°C) and stired soln. of Co-complex and norbornylene, stiring (20 min, 0°C and 30 min at 25°C).; Evapn. of solvent in vac., chromy. (Al2O3, CH2Cl2/hexane) gives dark red solid, (1)H NMR.;

Reference yield: 63.0%

: 498-66-8
norborn-2-ene

: 12078-25-0,12078-23-8
dicarbonylcyclopentadienylcobalt

: 501-65-5
diphenyl acetylene

: (η(5)-cyclopentadienyl)(.eta(4)-tetraphenylcyclobutadiene)cobalt(I)

: 113666-00-5
(5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-exo-hexahydro-1,4-methanonaphthalene)(η5-cyclopentadienyl)cobalt

: 113567-75-2
(5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-endo-hexahydro-1,4-methanonaphthalene)(η5-cyclopentadienyl)cobalt

: 62117-01-5
5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-hexahydro-1,4-methanonaphthalene

Guidance literature:: In toluene; Refluxing of mixt. (N2, 69 h).; Evapn. of solvent in high vac., column chromy. (Al2O3, CH2Cl2/hexane), evapn. of solvent in vac., preparative TLC (silica gel, CH2Cl2/hexane), crystn. (CH2Cl2/hexane), elem. anal.;

Reference yield:

: 113567-74-1
(5,6,7,8-η4-5,6,7,8-tetraphenyl-3a,4,4a,8a,9,9a-exo-hexahydro-4,9-methano-1H-benz{f}indene)(η5-cyclopentadienyl)cobalt

: 113666-02-7
(5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-exo-hexahydro-1,4-methanonaphthalene)(η5-methylcyclopentadienyl)cobalt

: 113626-31-6
(5,6,7,8-η4-5,6,7,8-tetraphenyl-3a,4,4a,8a,9,9a-endo-hexahydro-4,9-methano-1H-benz{f}indene)(η5-cyclopentadienyl)cobalt

: 113567-77-4
(5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-endo-hexahydro-1,4-methanonaphthalene)(η5-methylcyclopentadienyl)cobalt

: 113567-75-2
(5,6,7,8-η4-5,6,7,8-tetraphenyl-1,2,3,4,4a,8a-endo-hexahydro-1,4-methanonaphthalene)(η5-cyclopentadienyl)cobalt

: (5,6,7,8-η4-5,6,7,8-tetraphenyl-3a,4,4a,8a,9,9a-endo-hexahydro-4,9-methano-1H-benz{f}indene)(η5-methylcyclopentadienyl)cobalt

Guidance literature:: In further solvent(s); Dissolving in xylene-d10 in a NMR-tube, heating (150-160°C) up to 112 h.; (1)H NMR, (13)C NMR and MS.;