Ir(I)(1,5-cyclooctadiene)(1,2-bis(dicyclohexylphosphino)ethane) tetraphenylborate

Base Information

Chemical Name:Ir(I)(1,5-cyclooctadiene)(1,2-bis(dicyclohexylphosphino)ethane) tetraphenylborate
CAS No.:136638-26-1
Molecular Formula:C₂₄H₂₀B*C₃₄H₆₀IrP₂
Molecular Weight:1042.25
Hs Code.:

Synonyms:Ir(I)(1,5-cyclooctadiene)(1,2-bis(dicyclohexylphosphino)ethane) tetraphenylborate

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Chemical Property of Ir(I)(1,5-cyclooctadiene)(1,2-bis(dicyclohexylphosphino)ethane) tetraphenylborate

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Technology Process of Ir(I)(1,5-cyclooctadiene)(1,2-bis(dicyclohexylphosphino)ethane) tetraphenylborate

There total 1 articles about Ir(I)(1,5-cyclooctadiene)(1,2-bis(dicyclohexylphosphino)ethane) tetraphenylborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: chloro(1,5-cyclooctadiene)iridium(I) dimer

: 143-66-8
sodium tetraphenyl borate

: 23743-26-2
1,2-bis-(dicyclohexylphosphino)ethane

: 136638-26-1
Ir(I)(1,5-cyclooctadiene)(1,2-bis(dicyclohexylphosphino)ethane) tetraphenylborate

Guidance literature:: In dichloromethane; isopropyl alcohol; stirring Ir complex and phosphine ligand in CH2Cl2, 1h; addn. of NaBPh4 soln. (2-propanol); evapn. to half volume; pptn.; all under Ar; recrystn. from CH2Cl2/2-propanol; elem. anal.;
DOI:10.1016/0022-328X(91)83246-Z

Reference yield: 95.0%

: 136638-26-1
Ir(I)(1,5-cyclooctadiene)(1,2-bis(dicyclohexylphosphino)ethane) tetraphenylborate

: 136638-33-0
{Ir(CO)(1,5-cyclooctadiene)(1,2-bis(dicyclohexylphosphino)ethane)} tetraphenylborate

Guidance literature:: With CO; In dichloromethane; saturation of Ir complex soln. with CO (Ar), -10°C; decolorizing; pumping off CO; addn. of 2-propanol; concentration; pptn.; elem. anal.;
DOI:10.1016/0022-328X(91)83246-Z

Reference yield: 82.0%

: 136638-26-1
Ir(I)(1,5-cyclooctadiene)(1,2-bis(dicyclohexylphosphino)ethane) tetraphenylborate

: 136638-31-8
{Ir(CO)2(1,2-bis(dicyclohexylphosphino)ethane)} tetraphenylborate

Guidance literature:: With CO; In dichloromethane; stirring Ir complex soln. with CO (Ar), 10 min; addn. of 2-propanol; concentration; filtration; washing (light petroleum); drying (vac.); elem. anal.;
DOI:10.1016/0022-328X(91)83246-Z