3-nitro-2-azidobenzoic acid

Base Information

Chemical Name:3-nitro-2-azidobenzoic acid
CAS No.:10223-53-7
Molecular Formula:C₇H₄N₄O₄
Molecular Weight:208.133
Hs Code.:

Synonyms:3-nitro-2-azidobenzoic acid

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Chemical Property of 3-nitro-2-azidobenzoic acid

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Technology Process of 3-nitro-2-azidobenzoic acid

There total 1 articles about 3-nitro-2-azidobenzoic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 606-18-8
3-nitroanthranilic acid

: 10223-53-7
3-nitro-2-azidobenzoic acid

Guidance literature:: Multistep reaction; (i) H₂SO₄, AcOH, NaNO₂, (ii) aq. NaN₃;
DOI:10.1039/j29660001004

Reference yield: 23.0%

: 79-20-9
acetic acid methyl ester

: 10223-53-7
3-nitro-2-azidobenzoic acid

: C₁₀H₆N₆O₅

Guidance literature:: acetic acid methyl ester; 3-nitro-2-azidobenzoic acid; With sodium hydride; trifluoroacetyl chloride; In dichloromethane; at 0 ℃; for 0.25h; Inert atmosphere;

With 1-methyl-1H-imidazole; In dichloromethane; at -45 ℃; for 0.166667h; Further stages; Inert atmosphere;
DOI:10.1021/acs.joc.8b00222

Reference yield:

: 10223-53-7
3-nitro-2-azidobenzoic acid

: C₂₅H₁₉N₃O₅

Guidance literature:: Multi-step reaction with 2 steps

1.1: trifluoroacetyl chloride; sodium hydride / dichloromethane / 0.25 h / 0 °C / Inert atmosphere

1.2: 0.17 h / -45 °C / Inert atmosphere

2.1: copper(II) bis(trifluoromethanesulfonate) / dichloromethane / 24 h / 20 °C / Inert atmosphere

With copper(II) bis(trifluoromethanesulfonate); sodium hydride; trifluoroacetyl chloride; In dichloromethane;
DOI:10.1021/acs.joc.8b00222