Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OTf)2(DME)

Base Information

• Chemical Name: Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OTf)2(DME)
• CAS No.: 645391-49-7
• Molecular Formula: C₂₈H₃₉F₆MoNO₈S₂
• Molecular Weight: 791.682
• Mol file: 645391-49-7.mol

Synonyms:Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OTf)2(DME)

Chemical Property of Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OTf)2(DME)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OTf)2(DME)

There total 5 articles about Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OTf)2(DME) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

(2,6-disopropylphenylamido)(2,6-diisopropylphenylimido)bis(neophyl)molybdenum (126949-61-9) + trifluorormethanesulfonic acid (1493-13-6) → Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OTf)2(DME) (645391-49-7)

Guidance literature:

In 1,2-dimethoxyethane; byproducts: anilinium triflate, CH3(CH2C(CH3)2C6H5); soln. of CF3SO2OH is added dropwise to soln. of Mo-compd. at -30°C, mixt. is allowed to warm to 25°C and is stirred overnight (16 h); evapn., extn. with cold toluene, filtn. through Celite, filtrate is concentrated in vac., recrystd. (cold Et2O), elem. anal.;

DOI:10.1021/ja00166a023

Reference yield:

2,6-diisopropylbenzenamine (24544-04-5) → Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OTf)2(DME) (645391-49-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 2,6-lutidine; chlorotrimethylsilane / 1,2-dimethoxyethane

2: diethyl ether

3: 1,2-dimethoxyethane

With 2,6-lutidine; chlorotrimethylsilane; In 1,2-dimethoxyethane; diethyl ether;

DOI:10.1021/ja00166a023

Reference yield:

N-trimethylsilyl-2,6-diisopropylaniline (78923-65-6) → Mo(N-2,6-i-Pr2C6H3)(CHCMe2Ph)(OTf)2(DME) (645391-49-7)

Guidance literature:

Multi-step reaction with 3 steps

1: 2,6-lutidine; chlorotrimethylsilane / 1,2-dimethoxyethane

2: diethyl ether

3: 1,2-dimethoxyethane

With 2,6-lutidine; chlorotrimethylsilane; In 1,2-dimethoxyethane; diethyl ether;

DOI:10.1021/ja00166a023

upstream raw materials:

(2,6-disopropylphenylamido)(2,6-diisopropylphenylimido)bis(neophyl)molybdenum

trifluorormethanesulfonic acid

2-methyl-2-phenyl-1-propylmagnesium chloride

2,6-diisopropylbenzenamine

Downstream raw materials:

{(2-methyl-2-phenyl-propylidene)((2,6-diisopropylphenyl)imido)molybdenum(VI)bis(trifluoro-tert-butoxide)}

{(2-methyl-2-phenyl-propylidene)((2,6-diisopropylphenyl)imido)molybdenum(VI)bis(perfluoro-2-methyl-2-pentoxide)}

{(neophylidene)(2,6-diisopropylphenylimido)(2-tert-butylphenoxide)2 molybdenum}

{(neophylidene)(2,6-diisopropylphenylimido)(2,6-diisopropylpenoxide)2 molybdenum}