4-(4'-{4-[4'-(2,5-bis-hexyloxy-4-trimethylsilanylethynyl-phenylethynyl)-biphenyl-4-ylethynyl]-2,5-bis-hexyloxy-phenylethynyl}-biphenyl-4-yl)-2-methyl-but-3-yn-2-ol

Base Information

Chemical Name:4-(4'-{4-[4'-(2,5-bis-hexyloxy-4-trimethylsilanylethynyl-phenylethynyl)-biphenyl-4-ylethynyl]-2,5-bis-hexyloxy-phenylethynyl}-biphenyl-4-yl)-2-methyl-but-3-yn-2-ol
CAS No.:872173-86-9
Molecular Formula:C₇₆H₈₈O₅Si
Molecular Weight:1109.62
Hs Code.:

4-(4'-{4-[4'-(2,5-bis-hexyloxy-4-trimethylsilanylethynyl-phenylethynyl)-biphenyl-4-ylethynyl]-2,5-bis-hexyloxy-phenylethynyl}-biphenyl-4-yl)-2-methyl-but-3-yn-2-ol

Synonyms:4-(4'-{4-[4'-(2,5-bis-hexyloxy-4-trimethylsilanylethynyl-phenylethynyl)-biphenyl-4-ylethynyl]-2,5-bis-hexyloxy-phenylethynyl}-biphenyl-4-yl)-2-methyl-but-3-yn-2-ol

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Chemical Property of 4-(4'-{4-[4'-(2,5-bis-hexyloxy-4-trimethylsilanylethynyl-phenylethynyl)-biphenyl-4-ylethynyl]-2,5-bis-hexyloxy-phenylethynyl}-biphenyl-4-yl)-2-methyl-but-3-yn-2-ol

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Technology Process of 4-(4'-{4-[4'-(2,5-bis-hexyloxy-4-trimethylsilanylethynyl-phenylethynyl)-biphenyl-4-ylethynyl]-2,5-bis-hexyloxy-phenylethynyl}-biphenyl-4-yl)-2-methyl-but-3-yn-2-ol

There total 11 articles about 4-(4'-{4-[4'-(2,5-bis-hexyloxy-4-trimethylsilanylethynyl-phenylethynyl)-biphenyl-4-ylethynyl]-2,5-bis-hexyloxy-phenylethynyl}-biphenyl-4-yl)-2-methyl-but-3-yn-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 872173-79-0
4-{4'-iodo-[1,1'-biphenyl]-4-yl}-2-methylbut-3-yn-2-ol

: 872173-85-8
{4-[4'-(4-ethynyl-2,5-bis-hexyloxy-phenylethynyl)-biphenyl-4-ylethynyl]-2,5-bis-hexyloxy-phenylethynyl}-trimethyl-silane

: 872173-86-9
4-(4'-{4-[4'-(2,5-bis-hexyloxy-4-trimethylsilanylethynyl-phenylethynyl)-biphenyl-4-ylethynyl]-2,5-bis-hexyloxy-phenylethynyl}-biphenyl-4-yl)-2-methyl-but-3-yn-2-ol

Guidance literature:: With copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride; at 80 ℃; for 3h;
DOI:10.1021/jo051711o

Reference yield:

: 872173-78-9
1,4-dihexyloxy-2-(3-hydroxy-3-methylbutynyl)-5-iodobenzene

: 872173-86-9
4-(4'-{4-[4'-(2,5-bis-hexyloxy-4-trimethylsilanylethynyl-phenylethynyl)-biphenyl-4-ylethynyl]-2,5-bis-hexyloxy-phenylethynyl}-biphenyl-4-yl)-2-methyl-but-3-yn-2-ol

Guidance literature:: Multi-step reaction with 3 steps

1: 69 percent / triethylamine; CuI / Pd(PPh₃)2Cl₂ / 3.5 h / 60 °C

2: 77 percent / NaOH / toluene / 1 h / Heating

3: 85 percent / triethylamine; CuI / Pd(PPh₃)2Cl₂ / 3 h / 80 °C

With sodium hydroxide; copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In toluene; 1: Sonogashira coupling / 3: Sonogashira coupling;
DOI:10.1021/jo051711o

Reference yield:

: 3001-15-8
4,4'-diiodobiphenyl

: 872173-86-9
4-(4'-{4-[4'-(2,5-bis-hexyloxy-4-trimethylsilanylethynyl-phenylethynyl)-biphenyl-4-ylethynyl]-2,5-bis-hexyloxy-phenylethynyl}-biphenyl-4-yl)-2-methyl-but-3-yn-2-ol

Guidance literature:: Multi-step reaction with 6 steps

1: 43 percent / piperidine; CuI / Pd(PPh₃)2Cl₂ / tetrahydrofuran / 2 h / 50 °C

2: 86 percent / triethylamine; CuI / Pd(PPh₃)2Cl₂ / 3.5 h / 50 - 60 °C

3: 93 percent / NaOH / toluene / 1 h / Heating

4: 69 percent / triethylamine; CuI / Pd(PPh₃)2Cl₂ / 3.5 h / 60 °C

5: 77 percent / NaOH / toluene / 1 h / Heating

6: 85 percent / triethylamine; CuI / Pd(PPh₃)2Cl₂ / 3 h / 80 °C

With piperidine; sodium hydroxide; copper(l) iodide; triethylamine; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; toluene; 1: Sonogashira coupling / 2: Sonogashira coupling / 4: Sonogashira coupling / 6: Sonogashira coupling;
DOI:10.1021/jo051711o