phenacyl (5-fluoro-2,3,4-tri-O-acetyl-β-D-glucopyranosyl fluoride)uronate

Base Information

Chemical Name:phenacyl (5-fluoro-2,3,4-tri-O-acetyl-β-D-glucopyranosyl fluoride)uronate
CAS No.:374105-90-5
Molecular Formula:C₂₀H₂₀F₂O₁₀
Molecular Weight:458.37
Hs Code.:

Synonyms:phenacyl (5-fluoro-2,3,4-tri-O-acetyl-β-D-glucopyranosyl fluoride)uronate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of phenacyl (5-fluoro-2,3,4-tri-O-acetyl-β-D-glucopyranosyl fluoride)uronate

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Technology Process of phenacyl (5-fluoro-2,3,4-tri-O-acetyl-β-D-glucopyranosyl fluoride)uronate

There total 5 articles about phenacyl (5-fluoro-2,3,4-tri-O-acetyl-β-D-glucopyranosyl fluoride)uronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

: 374105-89-2
phenacyl (5-bromo-2,3,4-tri-O-acetyl-β-D-glucopyranosyl fluoride)uronate

: 374105-90-5
phenacyl (5-fluoro-2,3,4-tri-O-acetyl-β-D-glucopyranosyl fluoride)uronate

: phenacyl (5-fluoro-2,3,4-tri-O-acetyl-α-L-idopyranosyl fluoride)uronate

Guidance literature:: With silver tetrafluoroborate; In diethyl ether; at 20 ℃; for 1h;
DOI:10.1139/cjc-79-5-6-510

Reference yield:

: 6556-12-3,489-91-8,528-16-5,552-12-5,577-46-8,643-33-4,2240-07-5,6294-16-2,10133-02-5,18402-78-3,18968-14-4,21179-08-8,23018-83-9,33599-45-0,33599-46-1,46171-67-9,46171-69-1,46172-26-3,70021-34-0,71031-08-8,104195-06-4,106499-29-0,124817-72-7
D-glucuronic acid

: 374105-90-5
phenacyl (5-fluoro-2,3,4-tri-O-acetyl-β-D-glucopyranosyl fluoride)uronate

Guidance literature:: Multi-step reaction with 5 steps

1.1: 62 percent / H₂SO₄ / acetonitrile / 16 h / 20 °C

2.1: hydrazine acetate / dimethylformamide / Heating

2.2: 47 percent / Et₃N / ethyl acetate / 20 °C

3.1: 56 percent / DAST / CH₂Cl₂

4.1: 43 percent / N-bromosuccinimide / CCl₄ / 2 h / Irradiation

5.1: 12 percent / AgBF₄ / diethyl ether / 1 h / 20 °C

With N-Bromosuccinimide; silver tetrafluoroborate; sulfuric acid; hydrazinium monoacetate; 4,4'-diaminostilbene-2,2'-disulfonic acid; In tetrachloromethane; diethyl ether; dichloromethane; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1139/cjc-79-5-6-510

Reference yield:

: 374105-88-1
phenacyl (2,3,4-tri-O-acetyl-β-D-glucopyranosyl fluoride)uronate

: 374105-90-5
phenacyl (5-fluoro-2,3,4-tri-O-acetyl-β-D-glucopyranosyl fluoride)uronate

Guidance literature:: Multi-step reaction with 2 steps

1: 43 percent / N-bromosuccinimide / CCl₄ / 2 h / Irradiation

2: 12 percent / AgBF₄ / diethyl ether / 1 h / 20 °C

With N-Bromosuccinimide; silver tetrafluoroborate; In tetrachloromethane; diethyl ether;
DOI:10.1139/cjc-79-5-6-510