(S)-(E)-2-<<(Benzyloxy)methoxy>methyl>-1-<<(tert-butyldiphenylsilyl)oxy>methyl>non-3-en

Base Information

Chemical Name:(S)-(E)-2-<<(Benzyloxy)methoxy>methyl>-1-<<(tert-butyldiphenylsilyl)oxy>methyl>non-3-en
CAS No.:138513-57-2
Molecular Formula:C₃₄H₄₆O₃Si
Molecular Weight:530.823
Hs Code.:

Synonyms:(S)-(E)-2-<<(Benzyloxy)methoxy>methyl>-1-<<(tert-butyldiphenylsilyl)oxy>methyl>non-3-en

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Chemical Property of (S)-(E)-2-<<(Benzyloxy)methoxy>methyl>-1-<<(tert-butyldiphenylsilyl)oxy>methyl>non-3-en

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Technology Process of (S)-(E)-2-<<(Benzyloxy)methoxy>methyl>-1-<<(tert-butyldiphenylsilyl)oxy>methyl>non-3-en

There total 8 articles about (S)-(E)-2-<<(Benzyloxy)methoxy>methyl>-1-<<(tert-butyldiphenylsilyl)oxy>methyl>non-3-en which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 111-71-7
heptanal

: 138513-57-2
(S)-(E)-2-<<(Benzyloxy)methoxy>methyl>-1-<<(tert-butyldiphenylsilyl)oxy>methyl>non-3-en

Guidance literature:: Multi-step reaction with 7 steps

1: 58 percent / piperidinium acetate / benzene / Heating

2: 72 percent / lithium diisopropylamide / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / -78 °C

3: 14.06 g / LiAlH₄ / diethyl ether / a.) 0 deg C, 10 min, b.) room temperature, 3.5 h

4: 83 percent / Et₃N, DMAP / CH₂Cl₂ / 20 h / Ambient temperature

5: H₂O; propan-2-ol / pig pancreatic lipase, pH 7 buffer (K₂HPO₄-KH₂PO₄)

6: 1.) diisopropylethylamine, 2.) KOH / 1.) CH₂Cl₂, room temperature, 2.) MeOH

With dmap; potassium hydroxide; lithium aluminium tetrahydride; piperdinium acetate; triethylamine; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; hexane; dichloromethane; water; isopropyl alcohol; benzene;
DOI:10.1021/jo00031a039

Reference yield:

: 133490-80-9
(E)-1-Acetoxy-2-(acetoxymethyl)-3-nonene

: 138513-57-2
(S)-(E)-2-<<(Benzyloxy)methoxy>methyl>-1-<<(tert-butyldiphenylsilyl)oxy>methyl>non-3-en

Guidance literature:: Multi-step reaction with 3 steps

1: H₂O; propan-2-ol / pig pancreatic lipase, pH 7 buffer (K₂HPO₄-KH₂PO₄)

2: 1.) diisopropylethylamine, 2.) KOH / 1.) CH₂Cl₂, room temperature, 2.) MeOH

With potassium hydroxide; N-ethyl-N,N-diisopropylamine; In water; isopropyl alcohol;
DOI:10.1021/jo00031a039

Reference yield:

: 51615-31-7
heptylidene-malonic acid diethyl ester

: 138513-57-2
(S)-(E)-2-<<(Benzyloxy)methoxy>methyl>-1-<<(tert-butyldiphenylsilyl)oxy>methyl>non-3-en

Guidance literature:: Multi-step reaction with 6 steps

1: 72 percent / lithium diisopropylamide / tetrahydrofuran; hexamethylphosphoric acid triamide; hexane / -78 °C

2: 14.06 g / LiAlH₄ / diethyl ether / a.) 0 deg C, 10 min, b.) room temperature, 3.5 h

3: 83 percent / Et₃N, DMAP / CH₂Cl₂ / 20 h / Ambient temperature

4: H₂O; propan-2-ol / pig pancreatic lipase, pH 7 buffer (K₂HPO₄-KH₂PO₄)

5: 1.) diisopropylethylamine, 2.) KOH / 1.) CH₂Cl₂, room temperature, 2.) MeOH

With dmap; potassium hydroxide; lithium aluminium tetrahydride; triethylamine; N-ethyl-N,N-diisopropylamine; lithium diisopropyl amide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; diethyl ether; hexane; dichloromethane; water; isopropyl alcohol;
DOI:10.1021/jo00031a039