(5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-2-cyclohexen-1-one

Base Information

Chemical Name:(5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-2-cyclohexen-1-one
CAS No.:70552-73-7
Molecular Formula:C₁₆H₂₆O₃
Molecular Weight:266.381
Hs Code.:

Synonyms:(5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-2-cyclohexen-1-one

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Chemical Property of (5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-2-cyclohexen-1-one

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Technology Process of (5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-2-cyclohexen-1-one

There total 22 articles about (5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-2-cyclohexen-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 123453-96-3
(5S,6S)-5-(1-Ethoxy-ethoxymethyl)-6-((1S,2R)-1-hydroxy-3-methyl-2-phenylselanyl-butyl)-cyclohex-2-enone

: 70552-73-7
(5S,6R)-5-(1-Ethoxy-ethoxymethyl)-6-((E)-3-methyl-but-1-enyl)-cyclohex-2-enone

Guidance literature:: With methanesulfonyl chloride; triethylamine; In dichloromethane;
DOI:10.1016/S0040-4020(01)81464-2

Reference yield: 91.0%

: 123453-96-3
(5S,6S,1'R^*,2'R)-5-<(1-ethoxyethoxy)methyl>-6-(1'-hydroxy-3'-methyl-2'-phenylselenobutyl)-2-cyclohexen-1-one

: 70552-73-7
(5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-2-cyclohexen-1-one

Guidance literature:: With methanesulfonyl chloride; triethylamine; In dichloromethane; for 0.25h;
DOI:10.1016/S0040-4020(01)81464-2

Reference yield:

: 5708-19-0
(1S)-3-cyclohexenecarboxylic acid

: 70552-73-7
(5S,6R,1'Z)-5-<(1-ethoxyethoxy)methyl>-6-(3'-methyl-1'-butenyl)-2-cyclohexen-1-one

Guidance literature:: Multi-step reaction with 7 steps

1: KI-I₂, 0.5 m aq. NaHCO₃ / CH₂Cl₂; H₂O / 16 h

2: DBU / benzene / 8 h / Heating

3: LiAlH₄ / tetrahydrofuran / 1 h / Ambient temperature

4: MnO₂ / CHCl₃ / 26 h / Ambient temperature

5: 98.6 percent / PPTS / CH₂Cl₂ / Ambient temperature

6: 1) LDA / 1) -10 deg C to -5 deg C, 20 min, 2) -78 deg C

7: 91 percent / MsCl, NEt₃ / CH₂Cl₂ / 0.25 h

With manganese(IV) oxide; lithium aluminium tetrahydride; iodine; pyridinium p-toluenesulfonate; sodium hydrogencarbonate; methanesulfonyl chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; potassium iodide; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane; chloroform; water; benzene;
DOI:10.1016/S0040-4020(01)81464-2