methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose

Base Information

• Chemical Name: methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose
• CAS No.: 38993-01-0
• Molecular Formula: C₂₁H₂₀O₇
• Molecular Weight: 384.386
• Mol file: 38993-01-0.mol

Synonyms:methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose

Chemical Property of methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose

There total 12 articles about methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-mannopyranoside (50710-80-0) → methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-arabino-hexopyranosid-2-ulose (38993-01-0)

Guidance literature:

With tetrapropylammonium perruthennate; 4 A molecular sieve; 4-methylmorpholine N-oxide; In dichloromethane; for 3h; Ambient temperature;

DOI:10.1021/jo951194h

Reference yield: 83.5%

methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-galactopyranoside (86420-71-5) → methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-lyxo-hexopyranosidulose (38993-01-0,38993-02-1,86030-15-1,86030-16-2,109010-32-4,135759-87-4)

Guidance literature:

With phosphoric acid; dimethyl sulfoxide; dicyclohexyl-carbodiimide; for 24h; Ambient temperature;

Reference yield: 56.0%

methyl 3-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranoside (86420-73-7) → methyl 3-O-benzoyl-4,6-O-benzylidene-β-D-lyxo-hexopyranosidulose (38993-01-0,38993-02-1,86030-15-1,86030-16-2,109010-32-4,135759-87-4)

Guidance literature:

With phosphoric acid; dimethyl sulfoxide; dicyclohexyl-carbodiimide; for 24h; Ambient temperature;

upstream raw materials:

methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-mannopyranoside

methyl 3-O-benzoyl-4,6-O-benzylidene-β-D-galactopyranoside

benzoyl cyanide

methyl 4,6-O-(S)-benzylidene-β-D-galactopyranoside

Downstream raw materials:

methyl 3-O-benzoyl-4,6-O-benzylidene-β-D-lyxo-hexopyranosidulose 4-nitrophenylhydrazone

methyl 3-O-benzoyl-4,6-O-benzylidene-α-D-lyxo-hexopyranosidulose 4-nitrophenylhydrazone

methyl 4,6-O-benzylidene-2,3-dideoxy-2-phenylazo-α-D-threo-hex-2-enopyranoside

methyl 3-benzylamino-4,6-O-benzylidene-3-deoxy-α-D-lyxo(or xylo)-hexopyranosidulose phenylhydrazone