benzyl O-[3,4,6-tri-O-benzyl-2-deoxy-2-(2,4-dinitroanilino)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Base Information

Chemical Name:benzyl O-[3,4,6-tri-O-benzyl-2-deoxy-2-(2,4-dinitroanilino)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside
CAS No.:262599-41-7
Molecular Formula:C₆₇H₆₇N₃O₁₄
Molecular Weight:1138.28
Hs Code.:

Synonyms:benzyl O-[3,4,6-tri-O-benzyl-2-deoxy-2-(2,4-dinitroanilino)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Suppliers and Price of benzyl O-[3,4,6-tri-O-benzyl-2-deoxy-2-(2,4-dinitroanilino)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzyl O-[3,4,6-tri-O-benzyl-2-deoxy-2-(2,4-dinitroanilino)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzyl O-[3,4,6-tri-O-benzyl-2-deoxy-2-(2,4-dinitroanilino)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

There total 6 articles about benzyl O-[3,4,6-tri-O-benzyl-2-deoxy-2-(2,4-dinitroanilino)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 27851-29-2
benzyl 2,3,4-tri-O-benzyl-D-glucopyranoside

: 3,4,6-tri-O-benzyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranose

: 262599-41-7
benzyl O-[3,4,6-tri-O-benzyl-2-deoxy-2-(2,4-dinitroanilino)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: With silver trifluoromethanesulfonate; triethylamine; 4-Nitrobenzenesulfonyl chloride; In dichloromethane; at -60 - 0 ℃;
DOI:10.1246/bcsj.73.173

Reference yield:

: 3068-36-8
3,4,6-tri-O-acetyl-2-deoxy-2-(2,4-dinitroanilino)-α-D-glucopyranosyl bromide

: 262599-41-7
benzyl O-[3,4,6-tri-O-benzyl-2-deoxy-2-(2,4-dinitroanilino)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 6 steps

1: 57 percent / Hg(CN)2; HgBr₂ / acetonitrile / 20 °C

2: 0.39 g / NaOMe / methanol / 3 h / 20 °C

3: 91 percent / sodium hydride / dimethylformamide / 1 h / 0 - 20 °C

4: RhCl(Ph₃P)3 / ethanol; benzene; H₂O / 96 h / Heating

5: 420 mg / aq. HCl / acetone / 1 h / 45 °C

6: 95 percent / p-nitrobenzenesulfonyl chloride; silver trifluoromethanesulfonate; triethylamine / CH₂Cl₂ / -60 - 0 °C

With hydrogenchloride; RhCl(PPh₃)3; sodium methylate; silver trifluoromethanesulfonate; mercury(II) cyanide; sodium hydride; triethylamine; 4-Nitrobenzenesulfonyl chloride; mercury dibromide; In methanol; ethanol; dichloromethane; water; N,N-dimethyl-formamide; acetone; acetonitrile; benzene; 1: glycosylation / 2: Deacetylation / 3: Alkylation / 4: Isomerization / 5: Hydrolysis / 6: glycosylation;
DOI:10.1246/bcsj.73.173

Reference yield:

: 262599-19-9
allyl 2-deoxy-2-(2,4-dinitroanilino)-β-D-glucopyranoside

: 262599-41-7
benzyl O-[3,4,6-tri-O-benzyl-2-deoxy-2-(2,4-dinitroanilino)-β-D-glucopyranosyl]-(1->6)-2,3,4-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: 91 percent / sodium hydride / dimethylformamide / 1 h / 0 - 20 °C

2: RhCl(Ph₃P)3 / ethanol; benzene; H₂O / 96 h / Heating

3: 420 mg / aq. HCl / acetone / 1 h / 45 °C

4: 95 percent / p-nitrobenzenesulfonyl chloride; silver trifluoromethanesulfonate; triethylamine / CH₂Cl₂ / -60 - 0 °C

With hydrogenchloride; RhCl(PPh₃)3; silver trifluoromethanesulfonate; sodium hydride; triethylamine; 4-Nitrobenzenesulfonyl chloride; In ethanol; dichloromethane; water; N,N-dimethyl-formamide; acetone; benzene; 1: Alkylation / 2: Isomerization / 3: Hydrolysis / 4: glycosylation;
DOI:10.1246/bcsj.73.173