2-O-benzoyl-4,6-O-benzylidene-3-O-benzyl-β-D-glucopyranosyl-(1->3)-4,6-O-benzylidene-D-glucal

Base Information

Chemical Name:2-O-benzoyl-4,6-O-benzylidene-3-O-benzyl-β-D-glucopyranosyl-(1->3)-4,6-O-benzylidene-D-glucal
CAS No.:1380516-46-0
Molecular Formula:C₄₀H₃₈O₁₀
Molecular Weight:678.736
Hs Code.:

Synonyms:2-O-benzoyl-4,6-O-benzylidene-3-O-benzyl-β-D-glucopyranosyl-(1->3)-4,6-O-benzylidene-D-glucal

Suppliers and Price of 2-O-benzoyl-4,6-O-benzylidene-3-O-benzyl-β-D-glucopyranosyl-(1->3)-4,6-O-benzylidene-D-glucal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 2-O-benzoyl-4,6-O-benzylidene-3-O-benzyl-β-D-glucopyranosyl-(1->3)-4,6-O-benzylidene-D-glucal

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 2-O-benzoyl-4,6-O-benzylidene-3-O-benzyl-β-D-glucopyranosyl-(1->3)-4,6-O-benzylidene-D-glucal

There total 4 articles about 2-O-benzoyl-4,6-O-benzylidene-3-O-benzyl-β-D-glucopyranosyl-(1->3)-4,6-O-benzylidene-D-glucal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 63598-36-7,167074-37-5
4,6-O-benzylidene-D-glucal

: C₃₂H₃₅NO₆S₂

: 1380516-46-0
2-O-benzoyl-4,6-O-benzylidene-3-O-benzyl-β-D-glucopyranosyl-(1->3)-4,6-O-benzylidene-D-glucal

Guidance literature:: C₃₂H₃₅NO₆S₂; With 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; 1,2-dichloro-ethane; at 20 ℃; for 1h; Molecular sieve;

With copper(I) triflate benzene complex; In dichloromethane; 1,2-dichloro-ethane; at -50 ℃; for 0.166667h;

4,6-O-benzylidene-D-glucal; In dichloromethane; 1,2-dichloro-ethane; at -50 - -30 ℃; for 15.8333h; stereoselective reaction;
DOI:10.1021/ol301349w

Reference yield:

: 1380516-41-5
C₂₀H₂₀O₅

: 1380516-46-0
2-O-benzoyl-4,6-O-benzylidene-3-O-benzyl-β-D-glucopyranosyl-(1->3)-4,6-O-benzylidene-D-glucal

Guidance literature:: Multi-step reaction with 3 steps

1.1: tetrahydrofuran; methanol / 2.5 h / 0 - 20 °C

2.1: pyridine / 0 - 20 °C

3.1: 2,4,6-tri-tert-butylpyrimidine / dichloromethane; 1,2-dichloro-ethane / 1 h / 20 °C / Molecular sieve

3.2: 0.17 h / -50 °C

3.3: 15.83 h / -50 - -30 °C

With pyridine; 2,4,6-tri-tert-butylpyrimidine; In tetrahydrofuran; methanol; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/ol301349w

Reference yield:

: 110522-37-7,124579-04-0,128442-04-6,124579-02-8
1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-D-arabino-hex-1-enitol

: 1380516-46-0
2-O-benzoyl-4,6-O-benzylidene-3-O-benzyl-β-D-glucopyranosyl-(1->3)-4,6-O-benzylidene-D-glucal

Guidance literature:: Multi-step reaction with 4 steps

1.1: 3,3-dimethyldioxirane / dichloromethane / 1 h / 0 °C

2.1: tetrahydrofuran; methanol / 2.5 h / 0 - 20 °C

3.1: pyridine / 0 - 20 °C

4.1: 2,4,6-tri-tert-butylpyrimidine / dichloromethane; 1,2-dichloro-ethane / 1 h / 20 °C / Molecular sieve

4.2: 0.17 h / -50 °C

4.3: 15.83 h / -50 - -30 °C

With pyridine; 3,3-dimethyldioxirane; 2,4,6-tri-tert-butylpyrimidine; In tetrahydrofuran; methanol; dichloromethane; 1,2-dichloro-ethane;
DOI:10.1021/ol301349w