[(2-(C(H)=N(2,6-(i-Pr)2C₆H₃))-4,6-(t-Bu)2-phenoxide)CuCl]2

Base Information

• Chemical Name: [(2-(C(H)=N(2,6-(i-Pr)2C₆H₃))-4,6-(t-Bu)2-phenoxide)CuCl]2
• CAS No.: 1068620-39-2
• Molecular Formula: C₅₄H₇₆Cl₂Cu₂N₂O₂
• Molecular Weight: 983.208
• Mol file: 1068620-39-2.mol

Synonyms:[(2-(C(H)=N(2,6-(i-Pr)2C₆H₃))-4,6-(t-Bu)2-phenoxide)CuCl]2

Chemical Property of [(2-(C(H)=N(2,6-(i-Pr)2C₆H₃))-4,6-(t-Bu)2-phenoxide)CuCl]2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(2-(C(H)=N(2,6-(i-Pr)2C₆H₃))-4,6-(t-Bu)2-phenoxide)CuCl]2

There total 1 articles about [(2-(C(H)=N(2,6-(i-Pr)2C₆H₃))-4,6-(t-Bu)2-phenoxide)CuCl]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

copper dichloride + 2,4-di-tert-butyl-6-(2,6-diisopropylphenyliminomethyl)phenol (210882-24-9) → [(2-(C(H)=N(2,6-(i-Pr)2C6H3))-4,6-(t-Bu)2-phenoxide)CuCl]2 (1068620-39-2)

Guidance literature:

With NaH; In tetrahydrofuran; (N2); std. Schlenk technique; NaH (2 equiv.) was slowly added to soln. of ligand in THF; stirred for 1 h; filtered; filtrate added to CuCl2 (1.5equiv.); stirred for 24 h; filtered; solvent removed (vac.); crystd. (hexane/toluene, 1/1, -25°C); elem. anal.;

DOI:10.1021/om800625f

Reference yield:

[(2-(C(H)=N(2,6-(i-Pr)2C6H3))-4,6-(t-Bu)2-phenoxide)CuCl]2 (1068620-39-2) + trimethylaluminum (75-24-1) → [(2-(C(H)=N(2,6-(i-Pr)2C6H3))-4,6-(t-Bu)2-phenoxide)AlMe2] (353493-61-5) + [(2-(C(H)=N(2,6-(i-Pr)2C6H3))-4,6-(t-Bu)2-phenoxide)AlMeCl] (1068620-41-6)

Guidance literature:

In toluene; byproducts: Cu(Cl)Me; (N2); std. Schlenk technique; soln. of Al compd. (2 equiv.) in toluene was added dropwise to soln. of ligand in toluene; stirred at ambient temp. for 24 h; filtered; solvent removed (vac.);

DOI:10.1021/om800625f

upstream raw materials:

2,4-di-tert-butyl-6-(2,6-diisopropylphenyliminomethyl)phenol

Downstream raw materials:

[(2-(C(H)=N(2,6-(i-Pr)2C₆H₃))-4,6-(t-Bu)2-phenoxide)AlMe₂]

[(2-(C(H)=N(2,6-(i-Pr)2C₆H₃))-4,6-(t-Bu)2-phenoxide)AlMeCl]