OsCl₂((NC₅H₃C₆H₅)2)2

Base Information

• Chemical Name: OsCl₂((NC₅H₃C₆H₅)2)2
• CAS No.: 825614-85-5
• Molecular Formula: C₄₄H₃₂Cl₂N₄Os
• Molecular Weight: 877.871
• Mol file: 825614-85-5.mol

Synonyms:OsCl₂((NC₅H₃C₆H₅)2)2

Chemical Property of OsCl₂((NC₅H₃C₆H₅)2)2

Chemical Property:

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Technology Process of OsCl₂((NC₅H₃C₆H₅)2)2

There total 1 articles about OsCl₂((NC₅H₃C₆H₅)2)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium hexachloroosmate(IV) + 4,4'-diphenyl-2,2'-bipyridine (6153-92-0) → OsCl2((NC5H3C6H5)2)2 (825614-85-5)

Guidance literature:

With sodium dithionite; In water; N,N-dimethyl-formamide; (inert atm.); react. osmium complex with ligand in refluxing DMF for 3 h, filtration, washing with DMF, cooling to 0°C, addn. to an aq. soln. of sodium dithionite; filtration, washing with water;

DOI:10.1021/ja0176705

Reference yield: 90.0%

OsCl2((NC5H3C6H5)2)2 (825614-85-5) + 1,2-bis(diphenylarsino)ethane (4431-24-7) → [Os(II)bis(4,4'-diphenyl-2,2'-bipyridine)1,2-diphenylarseno)ethane](2+)

Guidance literature:

In further solvent(s); (inert atm.); refluxing a mixt. of osmium complex with ligand in a mixt.of 2,2'-ethoxyethoxyethanol with glycerol (75:25 vol.) for 2 h; elem. anal.;

DOI:10.1021/ja0176705

Reference yield: 85.0%

OsCl2((NC5H3C6H5)2)2 (825614-85-5) + heptafluorobutanoate (45048-62-2) + cis-1,2-bis-(diphenylphosphino)ethene (983-80-2) → [Os(II)bis(4,4'-diphenyl-2,2'-bipyridine)cis-1,2-bis(diphenylphosphino)ethylene]bis(heptafluorobutyrate)

Guidance literature:

In further solvent(s); (inert atm.); refluxing a mixt. of osmium complex with ligand in a mixt.of 2,2'-ethoxyethoxyethanol with glycerol (75:25 vol.) for 2 h, addn. t o an aq. soln. of anion; elem. anal.;

DOI:10.1021/ja0176705

upstream raw materials:

4,4'-diphenyl-2,2'-bipyridine

Refernces