methyl (Z)-3-<3-<4-(3-t-butyldimethylsilylether-1-propenyl)phenoxy>-4-methoxyphenyl> propionate

Base Information

Chemical Name:methyl (Z)-3-<3-<4-(3-t-butyldimethylsilylether-1-propenyl)phenoxy>-4-methoxyphenyl> propionate
CAS No.:168135-09-9
Molecular Formula:C₂₆H₃₆O₅Si
Molecular Weight:456.654
Hs Code.:

Synonyms:methyl (Z)-3-<3-<4-(3-t-butyldimethylsilylether-1-propenyl)phenoxy>-4-methoxyphenyl> propionate

Suppliers and Price of methyl (Z)-3-<3-<4-(3-t-butyldimethylsilylether-1-propenyl)phenoxy>-4-methoxyphenyl> propionate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (Z)-3-<3-<4-(3-t-butyldimethylsilylether-1-propenyl)phenoxy>-4-methoxyphenyl> propionate

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Technology Process of methyl (Z)-3-<3-<4-(3-t-butyldimethylsilylether-1-propenyl)phenoxy>-4-methoxyphenyl> propionate

There total 10 articles about methyl (Z)-3-<3-<4-(3-t-butyldimethylsilylether-1-propenyl)phenoxy>-4-methoxyphenyl> propionate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 168135-08-8
methyl-3-<3-<4-(3-t-butyldimethylsilylether-1-propynyl)phenoxy>-4-methoxyphenyl> propionate

: 168135-09-9
methyl (Z)-3-<3-<4-(3-t-butyldimethylsilylether-1-propenyl)phenoxy>-4-methoxyphenyl> propionate

Guidance literature:: With quinoline; Lindlar's catalyst; In benzene; for 3h; Ambient temperature;
DOI:10.1080/00397919508015470

Reference yield:

: 621-59-0
isovanillin

: 168135-09-9
methyl (Z)-3-<3-<4-(3-t-butyldimethylsilylether-1-propenyl)phenoxy>-4-methoxyphenyl> propionate

Guidance literature:: Multi-step reaction with 5 steps

1: 94 percent / pyridine, piperidine / 3 h / Heating

2: 97 percent / p-TsOH / 24 h / Heating

3: 100 percent / H₂ / 10percent Pd/C / aq. ethanol / Ambient temperature

4: 74 percent / CuO, K₂CO₃, pyridine / 12 h / 120 °C

5: 91 percent / quinoline / Lindlar catalyst / benzene / 3 h / Ambient temperature

With piperidine; pyridine; quinoline; hydrogen; potassium carbonate; toluene-4-sulfonic acid; copper(II) oxide; palladium on activated charcoal; Lindlar's catalyst; In ethanol; benzene;
DOI:10.1080/00397919508015470

Reference yield:

: 766-96-1
4-bromo-1-ethynylbenzene

: 168135-09-9
methyl (Z)-3-<3-<4-(3-t-butyldimethylsilylether-1-propenyl)phenoxy>-4-methoxyphenyl> propionate

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) EtMgBr / 1.) THF, 45 deg C, 1 h, 2.) THF, 45 deg C, 1 h

2: 99 percent / imidazole / dimethylformamide / 24 h / Ambient temperature

3: 74 percent / CuO, K₂CO₃, pyridine / 12 h / 120 °C

4: 91 percent / quinoline / Lindlar catalyst / benzene / 3 h / Ambient temperature

With pyridine; 1H-imidazole; quinoline; ethylmagnesium bromide; potassium carbonate; copper(II) oxide; Lindlar's catalyst; In N,N-dimethyl-formamide; benzene;
DOI:10.1080/00397919508015470