11-benzyl-9,9a-dihydro-6H-dibenzo[e,g]pyrido[1,2-a][1,4]diazocin-10(11H)-one

Base Information

Chemical Name:11-benzyl-9,9a-dihydro-6H-dibenzo[e,g]pyrido[1,2-a][1,4]diazocin-10(11H)-one
CAS No.:1259925-22-8
Molecular Formula:C₂₅H₂₂N₂O
Molecular Weight:366.462
Hs Code.:

Synonyms:11-benzyl-9,9a-dihydro-6H-dibenzo[e,g]pyrido[1,2-a][1,4]diazocin-10(11H)-one

Suppliers and Price of 11-benzyl-9,9a-dihydro-6H-dibenzo[e,g]pyrido[1,2-a][1,4]diazocin-10(11H)-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 11-benzyl-9,9a-dihydro-6H-dibenzo[e,g]pyrido[1,2-a][1,4]diazocin-10(11H)-one

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 11-benzyl-9,9a-dihydro-6H-dibenzo[e,g]pyrido[1,2-a][1,4]diazocin-10(11H)-one

There total 7 articles about 11-benzyl-9,9a-dihydro-6H-dibenzo[e,g]pyrido[1,2-a][1,4]diazocin-10(11H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1259925-20-6
7,8-diallyl-5-benzyl-7,8-dihydrodibenzo[e,g][1,4]diazocin-6(5H)-one

: 1259925-22-8
11-benzyl-9,9a-dihydro-6H-dibenzo[e,g]pyrido[1,2-a][1,4]diazocin-10(11H)-one

Guidance literature:: With Grubbs catalyst first generation; In dichloromethane; for 2h; Reflux;
DOI:10.1016/j.tetlet.2010.09.010

Reference yield:

: 33829-01-5
1,3-dihydro-3-[(2-bromophenyl)imino]-2H-indol-2-one

: 1259925-22-8
11-benzyl-9,9a-dihydro-6H-dibenzo[e,g]pyrido[1,2-a][1,4]diazocin-10(11H)-one

Guidance literature:: Multi-step reaction with 5 steps

1: indium; sodium iodide / N,N-dimethyl-formamide / Inert atmosphere

2: 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride / toluene / 2 h / 80 °C / Inert atmosphere

3: sodium iodide / N,N-dimethyl-formamide / 16 h / 20 °C / Inert atmosphere

4: caesium carbonate / N,N-dimethyl-formamide / 18 h / Inert atmosphere

5: Grubbs catalyst first generation / dichloromethane / 2 h / Inert atmosphere; Reflux

With Grubbs catalyst first generation; indium; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; caesium carbonate; sodium iodide; In dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1016/j.tet.2012.09.036

Reference yield:

: 1149390-47-5
7-allyl-7,8-dihydrodibenzo[e,g][1,4]diazocin-6(5H)-one

: 1259925-22-8
11-benzyl-9,9a-dihydro-6H-dibenzo[e,g]pyrido[1,2-a][1,4]diazocin-10(11H)-one

Guidance literature:: Multi-step reaction with 3 steps

1: sodium iodide / N,N-dimethyl-formamide / 16 h / 20 °C / Inert atmosphere

2: caesium carbonate / N,N-dimethyl-formamide / 18 h / Inert atmosphere

3: Grubbs catalyst first generation / dichloromethane / 2 h / Inert atmosphere; Reflux

With Grubbs catalyst first generation; caesium carbonate; sodium iodide; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/j.tet.2012.09.036