(2S,3S,4R)-3,4-Epoxy-4-(3-methoxyphenyl)-2-butanol

Base Information

Chemical Name:(2S,3S,4R)-3,4-Epoxy-4-(3-methoxyphenyl)-2-butanol
CAS No.:131829-55-5
Molecular Formula:C₁₁H₁₄O₃
Molecular Weight:194.23
Hs Code.:

Synonyms:(2S,3S,4R)-3,4-Epoxy-4-(3-methoxyphenyl)-2-butanol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3S,4R)-3,4-Epoxy-4-(3-methoxyphenyl)-2-butanol

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of (2S,3S,4R)-3,4-Epoxy-4-(3-methoxyphenyl)-2-butanol

There total 5 articles about (2S,3S,4R)-3,4-Epoxy-4-(3-methoxyphenyl)-2-butanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 131702-32-4
Benzoic acid (R)-1-[(2S,3S)-3-(3-methoxy-phenyl)-oxiranyl]-ethyl ester

: 131829-55-5
(2S,3S,4R)-3,4-Epoxy-4-(3-methoxyphenyl)-2-butanol

Guidance literature:: With potassium carbonate; In methanol; for 6h; Yield given; Ambient temperature;
DOI:10.1021/jo00002a048

Reference yield:

: 20766-31-8,30625-53-7
(E)-4-(3-methoxyphenyl)but-3-en-2-one

: 131829-55-5
(2S,3S,4R)-3,4-Epoxy-4-(3-methoxyphenyl)-2-butanol

Guidance literature:: Multi-step reaction with 4 steps

1: 96 percent / cerium(III) chloride heptahydrate, NaBH₄ / methanol / 1.) -78 deg C, 15 min; 2.) room temp., 30 min

2: 48 percent / L-(+)-diisopropyl tartrate, titanium tetraisopropoxide, 3.0 M tert-butyl hydroperoxide / CH₂Cl₂; 2,2,4-trimethyl-pentane / 3 h / -20 °C

3: triphenylphosphine, diethyl azodicarboxylate / benzene; tetrahydrofuran / 1 h / Ambient temperature

4: anhydr. K₂CO₃ / methanol / 6 h / Ambient temperature

With titanium(IV) isopropylate; tert.-butylhydroperoxide; sodium tetrahydroborate; cerium(III) chloride; L-(+)-diisopropyl tartrate; potassium carbonate; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; 2,2,4-trimethylpentane; dichloromethane; benzene;
DOI:10.1021/jo00002a048

Reference yield:

: 131702-30-2
(E)-1-(3-Methoxyphenyl)-1-buten-3-ol

: 131829-55-5
(2S,3S,4R)-3,4-Epoxy-4-(3-methoxyphenyl)-2-butanol

Guidance literature:: Multi-step reaction with 3 steps

1: 48 percent / L-(+)-diisopropyl tartrate, titanium tetraisopropoxide, 3.0 M tert-butyl hydroperoxide / CH₂Cl₂; 2,2,4-trimethyl-pentane / 3 h / -20 °C

2: triphenylphosphine, diethyl azodicarboxylate / benzene; tetrahydrofuran / 1 h / Ambient temperature

3: anhydr. K₂CO₃ / methanol / 6 h / Ambient temperature

With titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; potassium carbonate; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; 2,2,4-trimethylpentane; dichloromethane; benzene;
DOI:10.1021/jo00002a048