3,6-bis[4-(diphenylamino)phenyl]-9,10-phenanthrenequinone

Base Information

• Chemical Name: 3,6-bis[4-(diphenylamino)phenyl]-9,10-phenanthrenequinone
• CAS No.: 1415100-79-6
• Molecular Formula: C₅₀H₃₄N₂O₂
• Molecular Weight: 694.832
• Mol file: 1415100-79-6.mol

Synonyms:3,6-bis[4-(diphenylamino)phenyl]-9,10-phenanthrenequinone

Chemical Property of 3,6-bis[4-(diphenylamino)phenyl]-9,10-phenanthrenequinone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,6-bis[4-(diphenylamino)phenyl]-9,10-phenanthrenequinone

There total 3 articles about 3,6-bis[4-(diphenylamino)phenyl]-9,10-phenanthrenequinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

3,6-dibromo-phenanthrene-9,10-dione (53348-05-3) + [4-(5,5-dimethyl[1,3,2]dioxaborinan-2-yl)phenyl]diphenylamine (408359-97-7) → 3,6-bis[4-(diphenylamino)phenyl]-9,10-phenanthrenequinone (1415100-79-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium carbonate; In 1,2-dimethoxyethane; water; at 60 - 85 ℃; for 16h; Inert atmosphere;

DOI:10.1016/j.tet.2012.10.070

Reference yield: 85.0%

→ 3,6-bis[4-(diphenylamino)phenyl]-9,10-phenanthrenequinone (1415100-79-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; tetrabutylammomium bromide; potassium carbonate; In toluene; at 100 ℃; for 16h; Inert atmosphere;

Reference yield: 47.5%

4-(diphenylamino)phenylboronic pinacol ester (267221-88-5) + 3,6-dibromo-phenanthrene-9,10-dione (53348-05-3) → 3,6-bis[4-(diphenylamino)phenyl]-9,10-phenanthrenequinone (1415100-79-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In ethanol; water; toluene; for 8h; Inert atmosphere; Reflux;

DOI:10.1002/anie.202111172

upstream raw materials:

3,6-dibromo-phenanthrene-9,10-dione

[4-(5,5-dimethyl[1,3,2]dioxaborinan-2-yl)phenyl]diphenylamine

4-(diphenylamino)phenylboronic pinacol ester

Downstream raw materials:

C₅₄H₃₄N₆