(1,3-Dioxolan-2-ylmethyl)magnesium bromide

Base Information

• Chemical Name: (1,3-Dioxolan-2-ylmethyl)magnesium bromide
• CAS No.: 180675-22-3
• Molecular Formula: C4H7BrMgO2
• Molecular Weight: 191.31
• European Community (EC) Number: 629-669-2
• Mol file: 180675-22-3.mol

Synonyms:180675-22-3;(1,3-dioxolan-2-ylmethyl)magnesium bromide;Magnesium,bromo(1,3-dioxolan-2-ylmethyl)-;1,3-Dioxolan-2-ylmethylmagnesium bromide, 0.50 M in THF;1,3-Dioxolan-2-ylmethylmagnesium bromide, 0.50 M in 2-MeTHF;Magnesium, bromo(1,3-dioxolan-2-ylmethyl)-;((1,3-dioxolan-2-yl)methyl)magnesium bromide;MFCD01321271;SCHEMBL285800;ZDNTZRAFJZERSL-UHFFFAOYSA-M;AKOS015909032;4-HYDROXY-3-METHYLBENZYLALCOHOL;1,3-Dioxolan-2-ylmethylmagnesium bromide;2-[(bromomagnesio)methyl]-1,3-dioxolane;(1,3-Dioxolan-2-ylmethyl)magnesium bromide, 0.50 M in THF

Chemical Property of (1,3-Dioxolan-2-ylmethyl)magnesium bromide

Chemical Property:

• Vapor Pressure: 87.6mmHg at 25°C
• Boiling Point: 65-67 °C
• Flash Point: −4 °F
• PSA: 18.46000
• Density: 0.938 g/mL at 25 °C
• LogP: -2.69010
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 189.94798
• Heavy Atom Count: 8
• Complexity: 47.3

Purity/Quality:

98%,99%, ^*data from raw suppliers

(1,3-Dioxolan-2-ylmethyl)magnesium bromide solution 0.5 M in THF ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F+;Xn
• Hazard Codes: F,C,Xn
• Statements: 11-14-19-22-34-40-37-36/37/38
• Safety Statements: 16-26-33-36-36/37/39-45-36/37

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [CH2-]C1OCCO1.[Mg+2].[Br-]
• Uses: (1,3-Dioxolan-2-ylmethyl)magnesium bromide is a Grignard reagent that can be used to prepare:3-[11C]-Propionaldehyde, a key intermediate for the synthesis of radiolabeled compound [11C]SN-38, wherein SN-38 is 7-ethyl-10-hydroxy camptothecin.1-[(S)-2,2-Dimethyl-(1,3)-dioxolan-4-yl]-4-(1,3-dioxolan2-yl)-2-ol by reacting with D-glyceraldehyde, which is further used to synthesize unsaturated nucleosides.A bicyclo carboxylate intermediate, which is employed in the total synthesis of spirovibsanin A.