[1-(4'-bromo-2'-fluorobenzyl)-4-dimethylaminopyridinium]-bis(maleonitriledithiolato)nickel(III)

Base Information

• Chemical Name: [1-(4'-bromo-2'-fluorobenzyl)-4-dimethylaminopyridinium]-bis(maleonitriledithiolato)nickel(III)
• CAS No.: 951006-66-9
• Molecular Formula: C₈N₄NiS₄*C₁₄H₁₅BrFN₂
• Molecular Weight: 649.258
• Mol file: 951006-66-9.mol

Synonyms:[1-(4'-bromo-2'-fluorobenzyl)-4-dimethylaminopyridinium]-bis(maleonitriledithiolato)nickel(III)

Chemical Property of [1-(4'-bromo-2'-fluorobenzyl)-4-dimethylaminopyridinium]-bis(maleonitriledithiolato)nickel(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1-(4'-bromo-2'-fluorobenzyl)-4-dimethylaminopyridinium]-bis(maleonitriledithiolato)nickel(III)

There total 2 articles about [1-(4'-bromo-2'-fluorobenzyl)-4-dimethylaminopyridinium]-bis(maleonitriledithiolato)nickel(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.7%

[1-(4'-bromo-2'-fluorobenzyl)-4-dimethylaminopyridinium]-bis(maleonitriledithiolato)nickel(II) → [1-(4'-bromo-2'-fluorobenzyl)-4-dimethylaminopyridinium]-bis(maleonitriledithiolato)nickel(III) (951006-66-9)

Guidance literature:

With I₂; In acetonitrile; Ni(II)-complex dissolved in MeCN, then MeCN-soln. of I2 slowly added, mixt. stirred for 4 h, MeOH added, mixt. stood overnight; crystals filtered off, washed with MeOH and Et2O, dried in vac., elem. anal.;

DOI:10.1016/j.jpcs.2006.09.016

Reference yield:

1-[2′-fluoro-4′-bromobenzyl-4-dimethylaminopyridinium] bromide (951006-67-0) → [1-(4'-bromo-2'-fluorobenzyl)-4-dimethylaminopyridinium]-bis(maleonitriledithiolato)nickel(III) (951006-66-9)

Guidance literature:

Multi-step reaction with 2 steps

1: water

2: I₂ / acetonitrile

With I₂; In water; acetonitrile;

DOI:10.1016/j.jpcs.2006.09.016

upstream raw materials:

1-[2′-fluoro-4′-bromobenzyl-4-dimethylaminopyridinium] bromide