C₁₉H₁₆FNSi

Base Information

• Chemical Name: C₁₉H₁₆FNSi
• CAS No.: 1430235-43-0
• Molecular Formula: C₁₉H₁₆FNSi
• Molecular Weight: 305.427
• Mol file: 1430235-43-0.mol

Synonyms:C₁₉H₁₆FNSi

Chemical Property of C₁₉H₁₆FNSi

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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Technology Process of C₁₉H₁₆FNSi

There total 2 articles about C₁₉H₁₆FNSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C19H18FNSi (1430235-19-0) → C19H16FNS + C19H16FNSi (1430235-43-0)

Guidance literature:

With norborn-2-ene; 1,10-Phenanthroline; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; In tetrahydrofuran; at 90 ℃; for 12h; Overall yield = 68 %; Glovebox; Inert atmosphere; Schlenk technique;

DOI:10.1021/ol400977r

Reference yield:

diphenylsilane (775-12-2) + 2-fluoro-4-vinylpyridine (552331-57-4) → C19H16FNS + C19H16FNSi (1430235-43-0)

Guidance literature:

Multi-step reaction with 2 steps

1: bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; triphenylphosphine / tetrahydrofuran / 1 h / 90 °C / Glovebox; Inert atmosphere; Schlenk technique

2: (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 1,10-Phenanthroline; norborn-2-ene / tetrahydrofuran / 12 h / 90 °C / Glovebox; Inert atmosphere; Schlenk technique

With norborn-2-ene; bis(1,5-cyclooctadiene)nickel ⁽⁰⁾; 1,10-Phenanthroline; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; triphenylphosphine; In tetrahydrofuran;

DOI:10.1021/ol400977r

upstream raw materials:

C₁₉H₁₈FNSi

diphenylsilane

2-fluoro-4-vinylpyridine

Refernces