2-(trimethylsilyl)ethyl <2,3-bis-O-(phenylmethyl)-β-D-galactopyranosyl>-(1,4)-2,3,6-tris-O-(phenylmethyl)-β-D-glucopyranoside

Base Information

Chemical Name:2-(trimethylsilyl)ethyl <2,3-bis-O-(phenylmethyl)-β-D-galactopyranosyl>-(1,4)-2,3,6-tris-O-(phenylmethyl)-β-D-glucopyranoside
CAS No.:164525-86-4
Molecular Formula:C₅₂H₆₄O₁₁Si
Molecular Weight:893.159
Hs Code.:

Synonyms:2-(trimethylsilyl)ethyl <2,3-bis-O-(phenylmethyl)-β-D-galactopyranosyl>-(1,4)-2,3,6-tris-O-(phenylmethyl)-β-D-glucopyranoside

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Chemical Property of 2-(trimethylsilyl)ethyl <2,3-bis-O-(phenylmethyl)-β-D-galactopyranosyl>-(1,4)-2,3,6-tris-O-(phenylmethyl)-β-D-glucopyranoside

Chemical Property:

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Technology Process of 2-(trimethylsilyl)ethyl <2,3-bis-O-(phenylmethyl)-β-D-galactopyranosyl>-(1,4)-2,3,6-tris-O-(phenylmethyl)-β-D-glucopyranoside

There total 5 articles about 2-(trimethylsilyl)ethyl <2,3-bis-O-(phenylmethyl)-β-D-galactopyranosyl>-(1,4)-2,3,6-tris-O-(phenylmethyl)-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: {2-[(2R,3R,4S,5R,6R)-3,4-Bis-benzyloxy-6-benzyloxymethyl-5-((4aR,6S,7R,8S,8aS)-7,8-bis-benzyloxy-2,2-dimethyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxy)-tetrahydro-pyran-2-yloxy]-ethyl}-trimethyl-silane

: 164525-86-4
2-(trimethylsilyl)ethyl <2,3-bis-O-(phenylmethyl)-β-D-galactopyranosyl>-(1,4)-2,3,6-tris-O-(phenylmethyl)-β-D-glucopyranoside

Guidance literature:: With acetic acid; at 80 ℃; Yield given;
DOI:10.1021/ja960148b

Reference yield:

: 117253-25-5
2-(trimethylsilyl)ethyl 2,3,6-tri-O-benzyl-4-O-(2,3-di-O-benzyl-4,6-O-benzylidene-β-D-galactopyranosyl)-β-D-glucopyranoside

: 164525-86-4
2-(trimethylsilyl)ethyl <2,3-bis-O-(phenylmethyl)-β-D-galactopyranosyl>-(1,4)-2,3,6-tris-O-(phenylmethyl)-β-D-glucopyranoside

Guidance literature:: With trifluoroacetic acid; In dichloromethane; Yield given;
DOI:10.1016/0040-4039(96)00383-8

Reference yield:

: 115969-51-2
2-(trimethylsilyl)ethyl O-(β-D-galactopyranosyl)-(1->4)-β-D-glucopyranoside

: 164525-86-4
2-(trimethylsilyl)ethyl <2,3-bis-O-(phenylmethyl)-β-D-galactopyranosyl>-(1,4)-2,3,6-tris-O-(phenylmethyl)-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: p-TsOH*H₂O / dimethylformamide

2: NaH / dimethylformamide

3: TFA / CH₂Cl₂

With sodium hydride; toluene-4-sulfonic acid; trifluoroacetic acid; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/0040-4039(96)00383-8