Technology Process of C28H38O3Si
There total 1 articles about C28H38O3Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
lithium borohydride;
In
tetrahydrofuran;
at 0 - 20 ℃;
Inert atmosphere;
DOI:10.1002/anie.201103550
- Guidance literature:
-
With
dmap; triethylamine;
In
dichloromethane;
at 0 ℃;
for 2h;
Inert atmosphere;
DOI:10.1002/anie.201103550
- Guidance literature:
-
Multi-step reaction with 5 steps
1.1: dicobalt octacarbonyl / toluene / 1.5 h / 20 °C / Inert atmosphere
1.2: 12 h / 100 °C
2.1: tetra-(n-butyl)ammonium iodide; N-ethyl-N,N-diisopropylamine / dichloromethane / 15 h / 20 °C / Inert atmosphere
3.1: borane-THF; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole / tetrahydrofuran / 2 h / 20 °C / Inert atmosphere
4.1: sodium hydride / tetrahydrofuran; mineral oil / 0 - 20 °C / Inert atmosphere
4.2: 0 - 20 °C / Inert atmosphere
5.1: sodium hydrogencarbonate / 1,2-dichloro-benzene / 10 h / 170 °C / Inert atmosphere
With
dicobalt octacarbonyl; borane-THF; tetra-(n-butyl)ammonium iodide; sodium hydride; sodium hydrogencarbonate; N-ethyl-N,N-diisopropylamine; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole;
In
tetrahydrofuran; dichloromethane; 1,2-dichloro-benzene; toluene; mineral oil;
1.1: Pauson-Khand reaction / 1.2: Pauson-Khand reaction;
DOI:10.1002/anie.201103550
