(-)-1-((1S,2S,3R,4R)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone

Base Information

Chemical Name:(-)-1-((1S,2S,3R,4R)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone
CAS No.:201409-73-6
Molecular Formula:C₁₇H₂₀O₃S
Molecular Weight:304.41
Hs Code.:

Synonyms:(-)-1-((1S,2S,3R,4R)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone

Suppliers and Price of (-)-1-((1S,2S,3R,4R)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (-)-1-((1S,2S,3R,4R)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (-)-1-((1S,2S,3R,4R)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone

There total 3 articles about (-)-1-((1S,2S,3R,4R)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 201409-68-9
(5S,6R)-6-methyl-5-[(R)-tolylsulfinylacetyl]bicyclo[2.2.1]hept-2-ene

: 201409-73-6
(-)-1-((1S,2S,3R,4R)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone

Guidance literature:: With ammonium paramolybdate; dihydrogen peroxide; In methanol; water; at 0 - 20 ℃;
DOI:10.1055/s-0028-1083167

Reference yield:

: 503570-52-3
(E)-1-p-tolylsulfonyl-3-penten-2-one

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 503570-55-6
(+)-1-((1R,2R,3S,4S)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone

: 201409-73-6
(-)-1-((1S,2S,3R,4R)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone

: 1-(3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone

Guidance literature:: With copper(II) bis(trifluoromethanesulfonate); In dichloromethane; toluene; at 0 ℃; for 0.3h; Title compound not separated from byproducts.;
DOI:10.1021/jo8009227

Reference yield:

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 17609-16-4
p-CH₃C₆H₄SO₂CH₂Li

: 123492-60-4
3-crotonoyl-1,3-oxazolidin-2-one

: 503570-55-6
(+)-1-((1R,2R,3S,4S)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone

: 201409-73-6
(-)-1-((1S,2S,3R,4R)-3-methylbicyclo[2.2.1]hept-5-en-2-yl)-2-tosylethanone

Guidance literature:: cyclopenta-1,3-diene; 3-crotonoyl-1,3-oxazolidin-2-one; With titanium((4R,5R)-2,2-dimethyl-α,α,α',α'-tetraphenyl-1,3-dioxolane-4,5-dimethylate)Br2; In dichloromethane; at -78 ℃; for 20h; Molecular sieve; Inert atmosphere;

p-CH₃C₆H₄SO₂CH₂Li;
DOI:10.1055/s-0028-1083167