4,6-Methano-1,3,2-benzodioxaborole-2-methanamine

Base Information

Chemical Name:4,6-Methano-1,3,2-benzodioxaborole-2-methanamine
CAS No.:179324-86-8
Molecular Formula:C₁₅H₂₈BNO₂
Molecular Weight:265.204
Hs Code.:
Mol file:179324-86-8.mol

Synonyms:4,6-Methano-1,3,2-benzodioxaborole-2-methanamine;(R)-BoroLeu-(+)-Pinanediol;

Suppliers and Price of 4,6-Methano-1,3,2-benzodioxaborole-2-methanamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

American Custom Chemicals Corporation
(R)-BOROLEU-(+)-PINANEDIOL 95.00%
5MG
$ 499.58

Alichem
(R)-3-Methyl-1-((3aS,4S,6S,7aR)-3a,5,5-trimethylhexahydro-4,6-methanobenzo[d][1,3,2]dioxaborol-2-yl)butan-1-amine
1g
$ 1471.50

ACHEMBLOCK
(R)-Boroleu-(+)-pinanediol 95%
250MG
$ 315.00

Total 13 raw suppliers

Chemical Property of 4,6-Methano-1,3,2-benzodioxaborole-2-methanamine

Chemical Property:

Vapor Pressure:0.0102mmHg at 25°C
Refractive Index:1.61
Boiling Point:263.7 °C at 760 mmHg
Flash Point:113.3 °C
PSA：44.48000
Density:1.31 g/cm³
LogP:1.46670

Purity/Quality:

97% ^*data from raw suppliers

(R)-BOROLEU-(+)-PINANEDIOL 95.00% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 4,6-Methano-1,3,2-benzodioxaborole-2-methanamine

There total 8 articles about 4,6-Methano-1,3,2-benzodioxaborole-2-methanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: C₂₀H₃₆BNO₄

: 179324-86-8
(1R)-3-methyl-1-[(1S,2S,6R,8S)-2,9,9-trimethyl-3,5-dioxa-4-boratricyclo[6.1.1.0^2,6]decan-4-yl]butan-1-amine

Guidance literature:: With hydrogenchloride; palladium 10% on activated carbon; In methanol; ethyl acetate; at 40 - 50 ℃; for 4h; Reagent/catalyst; Solvent;

Reference yield: 89.5%

: C₂₃H₃₀BNO₄

: 179324-86-8
(1R)-3-methyl-1-[(1S,2S,6R,8S)-2,9,9-trimethyl-3,5-dioxa-4-boratricyclo[6.1.1.0^2,6]decan-4-yl]butan-1-amine

Guidance literature:: With hydrazine hydrate; In ethanol; at 20 ℃; Reagent/catalyst; Solvent;

Reference yield:

: 18680-27-8
pinanediol

: 179324-86-8
(1R)-3-methyl-1-[(1S,2S,6R,8S)-2,9,9-trimethyl-3,5-dioxa-4-boratricyclo[6.1.1.0^2,6]decan-4-yl]butan-1-amine

Guidance literature:: Multi-step reaction with 5 steps

1: diethyl ether / 8 h / 40 °C

2: toluene / 1.5 h / -65 - -55 °C / Inert atmosphere

3: iron(III) chloride / tetrahydrofuran / -45 - -40 °C

4: tetrahydrofuran / 40 °C / Inert atmosphere

5: hydrazine hydrate / ethanol / 20 °C

With iron(III) chloride; hydrazine hydrate; In tetrahydrofuran; diethyl ether; ethanol; toluene;