1-{bis-[3,5-bis-(trifluoromethyl)phenyl]phosphinoylethynyl}-2-methoxynaphthalene

Base Information

Chemical Name:1-{bis-[3,5-bis-(trifluoromethyl)phenyl]phosphinoylethynyl}-2-methoxynaphthalene
CAS No.:930807-29-7
Molecular Formula:C₂₉H₁₅F₁₂O₂P
Molecular Weight:654.391
Hs Code.:

Synonyms:1-{bis-[3,5-bis-(trifluoromethyl)phenyl]phosphinoylethynyl}-2-methoxynaphthalene

Suppliers and Price of 1-{bis-[3,5-bis-(trifluoromethyl)phenyl]phosphinoylethynyl}-2-methoxynaphthalene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1-{bis-[3,5-bis-(trifluoromethyl)phenyl]phosphinoylethynyl}-2-methoxynaphthalene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1-{bis-[3,5-bis-(trifluoromethyl)phenyl]phosphinoylethynyl}-2-methoxynaphthalene

There total 3 articles about 1-{bis-[3,5-bis-(trifluoromethyl)phenyl]phosphinoylethynyl}-2-methoxynaphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 917894-85-0
1-ethynyl-2-methoxynaphthalene

: 142421-57-6
bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine

: 930807-29-7
1-{bis-[3,5-bis-(trifluoromethyl)phenyl]phosphinoylethynyl}-2-methoxynaphthalene

Guidance literature:: 1-ethynyl-2-methoxynaphthalene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃;

bis(3,5-di(trifluoromethyl)phenyl)chlorophosphine; In tetrahydrofuran; hexane; at -78 - 25 ℃;

With dihydrogen peroxide; In tetrahydrofuran; hexane; water; at 20 ℃; for 0.5h;
DOI:10.1002/chem.200600826

Reference yield:

: 930807-48-0
1-(1-chlorovinyl)-2-methoxynaphthalene

: 930807-29-7
1-{bis-[3,5-bis-(trifluoromethyl)phenyl]phosphinoylethynyl}-2-methoxynaphthalene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 97 percent / n-BuLi; diisopropylamine / hexane; tetrahydrofuran / -78 - 20 °C

2.1: n-BuLi / hexane; tetrahydrofuran / -78 - 0 °C

2.2: hexane; tetrahydrofuran / -78 - 25 °C

2.3: 90 percent / hydrogen peroxide / hexane; tetrahydrofuran; H₂O / 0.5 h / 20 °C

With n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane;
DOI:10.1002/chem.200600826

Reference yield:

: 5672-94-6
1-acetyl-2-methoxynaphthalene

: 930807-29-7
1-{bis-[3,5-bis-(trifluoromethyl)phenyl]phosphinoylethynyl}-2-methoxynaphthalene

Guidance literature:: Multi-step reaction with 3 steps

1.1: PCl₃; PCl₅ / benzene / 24 h / 20 °C

2.1: 97 percent / n-BuLi; diisopropylamine / hexane; tetrahydrofuran / -78 - 20 °C

3.1: n-BuLi / hexane; tetrahydrofuran / -78 - 0 °C

3.2: hexane; tetrahydrofuran / -78 - 25 °C

3.3: 90 percent / hydrogen peroxide / hexane; tetrahydrofuran; H₂O / 0.5 h / 20 °C

With n-butyllithium; phosphorus pentachloride; diisopropylamine; phosphorus trichloride; In tetrahydrofuran; hexane; benzene;
DOI:10.1002/chem.200600826