1-bromo-2-iodo-3,5-dimethylbenzene

Base Information

• Chemical Name: 1-bromo-2-iodo-3,5-dimethylbenzene
• CAS No.: 933671-83-1
• Molecular Formula: C₈H₈BrI
• Molecular Weight: 310.96
• Mol file: 933671-83-1.mol

Synonyms:1-bromo-2-iodo-3,5-dimethylbenzene

Chemical Property of 1-bromo-2-iodo-3,5-dimethylbenzene

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

1-Bromo-2-iodo-3,5-dimethylbenzene ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-bromo-2-iodo-3,5-dimethylbenzene

There total 1 articles about 1-bromo-2-iodo-3,5-dimethylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

2-bromo-4,6-dimethylaniline (41825-73-4) → 1-bromo-2-iodo-3,5-dimethylbenzene (933671-83-1)

Guidance literature:

2-bromo-4,6-dimethylaniline; With hydrogenchloride; sodium nitrite; at 0 ℃; for 0.5h;

With potassium iodide; In water; at 20 ℃; for 12h; Further stages.;

DOI:10.1002/anie.200703763

Reference yield: 88.0%

1-bromo-2-iodo-3,5-dimethylbenzene (933671-83-1) + trimethylsilylacetylene (1066-54-2) → C13H17BrSi

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; Inert atmosphere; Schlenk technique;

DOI:10.1002/chem.201504937

Reference yield: 85.0%

tris-iso-propylsilyl acetylene (89343-06-6) + 1-bromo-2-iodo-3,5-dimethylbenzene (933671-83-1) → ((2-bromo-4,6-dimethylphenyl)ethynyl)triisopropylsilane

Guidance literature:

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; In tetrahydrofuran; at 25 ℃; for 12h; Inert atmosphere;

DOI:10.1002/asia.202100756

upstream raw materials:

2-bromo-4,6-dimethylaniline

Downstream raw materials:

2,4-dimethylphenyl phenyl sulfone

3,5-dimethyl-1-(phenylsulphonyl)benzene

3,5-dimethyl-1,2-bis(phenylsulphonyl)benzene

Refernces

• 1、 -. "GRAPHENE NANORIBBONS WITH CONTROLLED ZIG-ZAG EDGE AND COVE EDGE CONFIGURATION". Page/Page column 47; 48. . Retrieved 2015/09/22.
• 2、 Novi, Marino,Garbarino, Giacomo,Petrillo, Giovanni,Dell'Erba, Carlo. "Electrochemical Reduction of Some o-Bis(phenylsulphonyl)benzene Derivatives. Effect of the Substrate Structure and of the Addition of Bases on the Product Distribution.". . p. 623 - 632. Retrieved 2007/10/02.