[2,6-(tBuOCH₂)2C₆H₃]PPh₂

Base Information

• Chemical Name: [2,6-(tBuOCH₂)2C₆H₃]PPh₂
• CAS No.: 1277189-70-4
• Molecular Formula: C₂₈H₃₅O₂P
• Molecular Weight: 434.558
• Mol file: 1277189-70-4.mol

Synonyms:[2,6-(tBuOCH₂)2C₆H₃]PPh₂

Chemical Property of [2,6-(tBuOCH₂)2C₆H₃]PPh₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of [2,6-(tBuOCH₂)2C₆H₃]PPh₂

There total 1 articles about [2,6-(tBuOCH₂)2C₆H₃]PPh₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,6-bis(tert-butoxymethyl)phenyllithium + chloro-diphenylphosphine (1079-66-9,74391-44-9) → [2,6-(tBuOCH2)2C6H3]PPh2 (1277189-70-4)

Guidance literature:

In hexane; for 24h; Inert atmosphere;

DOI:10.1002/aoc.1737

Reference yield: 97.0%

trimethylsilylazide (4648-54-8) + [2,6-(tBuOCH2)2C6H3]PPh2 (1277189-70-4) → C31H44NO2PSi (1402616-26-5)

Guidance literature:

In toluene; at 85 ℃; for 168h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.jorganchem.2012.08.003

Reference yield:

[2,6-(tBuOCH2)2C6H3]PPh2 (1277189-70-4) → C28H36NO2P (1402616-27-6)

Guidance literature:

Multi-step reaction with 3 steps

1: toluene / 168 h / 85 °C / Inert atmosphere; Schlenk technique

2: trimethylsilylazide; water / toluene / 72 h / Inert atmosphere; Schlenk technique

3: n-butyllithium / toluene / 0.5 h / -78 °C / Inert atmosphere; Schlenk technique

With n-butyllithium; trimethylsilylazide; water; In toluene;

DOI:10.1016/j.jorganchem.2012.08.003

upstream raw materials:

chloro-diphenylphosphine

Downstream raw materials:

C₃₁H₄₄NO₂PSi

C₂₈H₃₆NO₂P