Technology Process of (2',9'-dimethylpyrazo[5',6'-e]-1',10'-phenanthroline)[b]-meso-tetramesitylporphyrinatocopper(II)
There total 1 articles about (2',9'-dimethylpyrazo[5',6'-e]-1',10'-phenanthroline)[b]-meso-tetramesitylporphyrinatocopper(II) which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
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With
trifluoroacetic acid;
In
dichloromethane;
CF3COOH was added to soln. of ligand and Cu complex in CH2Cl2 at refluxunder N2, mixt. was heated at reflux overnight in the dark, cooled to room temp., mixt. was stirred over aq. soln. of NaHCO3; washed with water, brine, dried over Na2SO4, soln. was loaded onto silica gel column packed with CH2Cl2, eluted with a gradient of MeOH;
DOI:10.1021/ic990914q
