C₁₄H₁₆O

Base Information

• Chemical Name: C₁₄H₁₆O
• CAS No.: 1312319-96-2
• Molecular Formula: C₁₄H₁₆O
• Molecular Weight: 200.28
• Mol file: 1312319-96-2.mol

Synonyms:C₁₄H₁₆O

Chemical Property of C₁₄H₁₆O

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₄H₁₆O

There total 3 articles about C₁₄H₁₆O which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C20H32OSi (1312320-06-1) → C14H16O (1312319-96-2)

Guidance literature:

With Dess-Martin periodane; In dichloromethane; at 0 - 20 ℃;

DOI:10.1021/ja203824v

Reference yield:

C20H32O2Si → C14H16O (1312319-96-2)

Guidance literature:

Multi-step reaction with 2 steps

1: di-isopropyl azodicarboxylate; 2-nitrobenzenesulfonyl hydrazide; triphenylphosphine / tetrahydrofuran / 22 h / -15 - 20 °C

2: Dess-Martin periodane / dichloromethane / 0 - 20 °C

With di-isopropyl azodicarboxylate; 2-nitrobenzenesulfonyl hydrazide; Dess-Martin periodane; triphenylphosphine; In tetrahydrofuran; dichloromethane;

DOI:10.1021/ja203824v

Reference yield:

4-phenyl-1,1-dibromo-1-butene (119405-97-9) → C14H16O (1312319-96-2)

Guidance literature:

Multi-step reaction with 3 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 2 h / -78 °C

1.2: 2 h / -78 - 20 °C

2.1: di-isopropyl azodicarboxylate; 2-nitrobenzenesulfonyl hydrazide; triphenylphosphine / tetrahydrofuran / 22 h / -15 - 20 °C

3.1: Dess-Martin periodane / dichloromethane / 0 - 20 °C

With n-butyllithium; di-isopropyl azodicarboxylate; 2-nitrobenzenesulfonyl hydrazide; Dess-Martin periodane; triphenylphosphine; In tetrahydrofuran; hexane; dichloromethane;

DOI:10.1021/ja203824v

upstream raw materials:

C₂₀H₃₂OSi

4-phenyl-1,1-dibromo-1-butene

Downstream raw materials:

C₁₄H₁₆O

C₁₆H₁₈O

C₁₉H₂₄O₃