(Z)-4-bromo-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester

Base Information

• Chemical Name: (Z)-4-bromo-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester
• CAS No.: 153805-72-2
• Molecular Formula: C₁₃H₁₅BrO₃
• Molecular Weight: 299.164
• Mol file: 153805-72-2.mol

Synonyms:(Z)-4-bromo-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester

Chemical Property of (Z)-4-bromo-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester

Chemical Property:

Purity/Quality:

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MSDS Files:

Useful:

Technology Process of (Z)-4-bromo-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester

There total 2 articles about (Z)-4-bromo-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

3-(3-methoxyphenyl)-2-butenoic acid ethyl ester (7706-83-4) → (Z)-4-bromo-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester (153805-72-2)

Guidance literature:

With N-Bromosuccinimide; dibenzoyl peroxide; for 24h; chemoselective reaction; Reflux;

DOI:10.3390/molecules180910266

Reference yield:

(E)-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester (7706-83-4) → (Z)-4-bromo-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester (153805-72-2)

Guidance literature:

With N-Bromosuccinimide; dibenzoyl peroxide; In tetrachloromethane; for 10h; Heating;

DOI:10.1021/ol702193v

Reference yield: 86.0%

thiourea (17356-08-0) + (Z)-4-bromo-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester (153805-72-2) → C14H19N2O3S(1+)*Br(1-)

Guidance literature:

In ethanol; for 5h; Heating;

upstream raw materials:

(E)-3-(3-methoxyphenyl)-2-butenoic acid ethyl ester

3-(3-methoxyphenyl)-2-butenoic acid ethyl ester