(4S,5S)-1,3-dibenzyl-4,5-bis[(S)-1-p-nitrobenzoyloxyethyl]imidazolidin-2-one

Base Information

Chemical Name:(4S,5S)-1,3-dibenzyl-4,5-bis[(S)-1-p-nitrobenzoyloxyethyl]imidazolidin-2-one
CAS No.:872175-16-1
Molecular Formula:C₃₅H₃₂N₄O₉
Molecular Weight:652.66
Hs Code.:

Synonyms:(4S,5S)-1,3-dibenzyl-4,5-bis[(S)-1-p-nitrobenzoyloxyethyl]imidazolidin-2-one

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Chemical Property of (4S,5S)-1,3-dibenzyl-4,5-bis[(S)-1-p-nitrobenzoyloxyethyl]imidazolidin-2-one

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Technology Process of (4S,5S)-1,3-dibenzyl-4,5-bis[(S)-1-p-nitrobenzoyloxyethyl]imidazolidin-2-one

There total 9 articles about (4S,5S)-1,3-dibenzyl-4,5-bis[(S)-1-p-nitrobenzoyloxyethyl]imidazolidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 872175-13-8
(4S,5S)-1,3-dibenzyl-4,5-bis((R)-1-hydroxyethyl)imidazolidin-2-one

: 62-23-7
4-nitro-benzoic acid

: 872175-16-1
(4S,5S)-1,3-dibenzyl-4,5-bis[(S)-1-p-nitrobenzoyloxyethyl]imidazolidin-2-one

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at 20 ℃; for 4h;
DOI:10.1002/adsc.200404286

Reference yield:

: 872175-12-7
(4S,5S)-4,5-diacetyl-1,3-dibenzylimidazolidin-2-one

: 872175-16-1
(4S,5S)-1,3-dibenzyl-4,5-bis[(S)-1-p-nitrobenzoyloxyethyl]imidazolidin-2-one

Guidance literature:: Multi-step reaction with 4 steps

1: Dibal-H / methanol / 3 h / -78 °C

2: 40 percent / Et₃N; DMPA / CH₂Cl₂ / 4 h / 20 °C

3: 97 percent / K₂CO₃ / methanol; CH₂Cl₂ / 1 h / 20 °C

4: 91 percent / Ph₃P; DEAD / tetrahydrofuran / 4 h / 20 °C

With 0,2,4-dichlorophenyl-0-methylisopropylamidothiophosphate; diisobutylaluminium hydride; potassium carbonate; triethylamine; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1002/adsc.200404286

Reference yield:

: 872175-09-2
(4S,5S)-1,3-dibenzylimidazolidin-2-one-4,5-dicarboxylic acid

: 872175-16-1
(4S,5S)-1,3-dibenzyl-4,5-bis[(S)-1-p-nitrobenzoyloxyethyl]imidazolidin-2-one

Guidance literature:: Multi-step reaction with 7 steps

1: 95 percent / chlorotrimethylsilane / 12 h / 20 °C

2: iPrMgBr / tetrahydrofuran / 0.33 h / -28 °C

3: 0.58 g / tetrahydrofuran / 12 h / 20 °C

4: Dibal-H / methanol / 3 h / -78 °C

5: 40 percent / Et₃N; DMPA / CH₂Cl₂ / 4 h / 20 °C

6: 97 percent / K₂CO₃ / methanol; CH₂Cl₂ / 1 h / 20 °C

7: 91 percent / Ph₃P; DEAD / tetrahydrofuran / 4 h / 20 °C

With chloro-trimethyl-silane; 0,2,4-dichlorophenyl-0-methylisopropylamidothiophosphate; isopropylmagnesium bromide; diisobutylaluminium hydride; potassium carbonate; triethylamine; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1002/adsc.200404286