1-N-(phenyl 1,7-dideoxy-2,3,4,6-tetra-O-benzyl-1-thio-D-glycero-α-D-mannoheptopyranosid-7-yl)-4,5-dihydroxymethyl-1H-1,2,3-triazole

Base Information

Chemical Name:1-N-(phenyl 1,7-dideoxy-2,3,4,6-tetra-O-benzyl-1-thio-D-glycero-α-D-mannoheptopyranosid-7-yl)-4,5-dihydroxymethyl-1H-1,2,3-triazole
CAS No.:1345664-82-5
Molecular Formula:C₄₅H₄₇N₃O₇S
Molecular Weight:773.95
Hs Code.:

Synonyms:1-N-(phenyl 1,7-dideoxy-2,3,4,6-tetra-O-benzyl-1-thio-D-glycero-α-D-mannoheptopyranosid-7-yl)-4,5-dihydroxymethyl-1H-1,2,3-triazole

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Chemical Property of 1-N-(phenyl 1,7-dideoxy-2,3,4,6-tetra-O-benzyl-1-thio-D-glycero-α-D-mannoheptopyranosid-7-yl)-4,5-dihydroxymethyl-1H-1,2,3-triazole

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Technology Process of 1-N-(phenyl 1,7-dideoxy-2,3,4,6-tetra-O-benzyl-1-thio-D-glycero-α-D-mannoheptopyranosid-7-yl)-4,5-dihydroxymethyl-1H-1,2,3-triazole

There total 10 articles about 1-N-(phenyl 1,7-dideoxy-2,3,4,6-tetra-O-benzyl-1-thio-D-glycero-α-D-mannoheptopyranosid-7-yl)-4,5-dihydroxymethyl-1H-1,2,3-triazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 50.0%

: 110-65-6
1,4-dihydroxybut-2-yne

: 1345664-79-0
phenyl 7-azido-1,7-dideoxy-2,3,4,6-tetra-O-benzyl-1-thio-D-glycero-α-D-mannoheptopyranoside

: 1345664-82-5
1-N-(phenyl 1,7-dideoxy-2,3,4,6-tetra-O-benzyl-1-thio-D-glycero-α-D-mannoheptopyranosid-7-yl)-4,5-dihydroxymethyl-1H-1,2,3-triazole

Guidance literature:: at 110 ℃; for 24h; Inert atmosphere; neat (no solvent);
DOI:10.1002/chem.201100396

Reference yield:

: 1345664-76-7
phenyl 1-deoxy-2,3,4,6-tetra-O-benzyl-1-thio-D-glycero-α-D-manno-heptopyranoside

: 1345664-82-5
1-N-(phenyl 1,7-dideoxy-2,3,4,6-tetra-O-benzyl-1-thio-D-glycero-α-D-mannoheptopyranosid-7-yl)-4,5-dihydroxymethyl-1H-1,2,3-triazole

Guidance literature:: Multi-step reaction with 3 steps

1: dmap / dichloromethane / 1 h / 0 - 20 °C / Inert atmosphere

2: sodium azide; tetrabutylammomium bromide / N,N-dimethyl-formamide / 24 h / 90 °C / Inert atmosphere

3: 24 h / 110 °C / Inert atmosphere; neat (no solvent)

With dmap; sodium azide; tetrabutylammomium bromide; In dichloromethane; N,N-dimethyl-formamide; 3: Huisgen cycloaddidion;
DOI:10.1002/chem.201100396

Reference yield:

: C₄₂H₄₄O₈S₂

: 1345664-82-5
1-N-(phenyl 1,7-dideoxy-2,3,4,6-tetra-O-benzyl-1-thio-D-glycero-α-D-mannoheptopyranosid-7-yl)-4,5-dihydroxymethyl-1H-1,2,3-triazole

Guidance literature:: Multi-step reaction with 2 steps

1: sodium azide; tetrabutylammomium bromide / N,N-dimethyl-formamide / 24 h / 90 °C / Inert atmosphere

2: 24 h / 110 °C / Inert atmosphere; neat (no solvent)

With sodium azide; tetrabutylammomium bromide; In N,N-dimethyl-formamide; 2: Huisgen cycloaddidion;
DOI:10.1002/chem.201100396