1-methyl-3-benzylbenzimidazolium bis(maleonitrile-dithiolato)nickelate(III)

Base Information

• Chemical Name: 1-methyl-3-benzylbenzimidazolium bis(maleonitrile-dithiolato)nickelate(III)
• CAS No.: 856770-24-6
• Molecular Formula: C₈N₄NiS₄*C₁₅H₁₅N₂
• Molecular Weight: 562.366
• Mol file: 856770-24-6.mol

Synonyms:1-methyl-3-benzylbenzimidazolium bis(maleonitrile-dithiolato)nickelate(III)

Chemical Property of 1-methyl-3-benzylbenzimidazolium bis(maleonitrile-dithiolato)nickelate(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-methyl-3-benzylbenzimidazolium bis(maleonitrile-dithiolato)nickelate(III)

There total 2 articles about 1-methyl-3-benzylbenzimidazolium bis(maleonitrile-dithiolato)nickelate(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

1-methyl-3-benzylbenzimidazolium bis(maleonitrile-dithiolato)nickelate(II) → 1-methyl-3-benzylbenzimidazolium bis(maleonitrile-dithiolato)nickelate(III) (856770-24-6)

Guidance literature:

With I₂; In acetonitrile; soln. of I2 (0.59 mmol) in MeCN slowly added to soln. of Ni complex salt(1.0 mmol) in MeCN; stirring for 15 min; MeOH added; mixt. stored overnight; crystals filtered off, washed with MeOH and dried under vac.; elem. anal.;

DOI:10.1016/j.molstruc.2005.03.002

Reference yield:

1-benzyl-3-methyl-1H-benzimidazol-3-ium iodide (56463-13-9) → 1-methyl-3-benzylbenzimidazolium bis(maleonitrile-dithiolato)nickelate(III) (856770-24-6)

Guidance literature:

Multi-step reaction with 2 steps

1: water

2: I₂ / acetonitrile

With I₂; In water; acetonitrile;

DOI:10.1016/j.molstruc.2005.03.002

upstream raw materials:

1-benzyl-3-methyl-1H-benzimidazol-3-ium iodide