Oxiranecarboxaldehyde, 3-methyl-3-(3-pentenyl)-, [2R-[2alpha,3beta(Z)]]- (9CI)

Base Information

Chemical Name:Oxiranecarboxaldehyde, 3-methyl-3-(3-pentenyl)-, [2R-[2alpha,3beta(Z)]]- (9CI)
CAS No.:176695-89-9
Molecular Formula:C₉H₁₄O₂
Molecular Weight:154.209
Hs Code.:
Mol file:176695-89-9.mol

Synonyms:Oxiranecarboxaldehyde, 3-methyl-3-(3-pentenyl)-, [2R-[2alpha,3beta(Z)]]- (9CI)

Suppliers and Price of Oxiranecarboxaldehyde, 3-methyl-3-(3-pentenyl)-, [2R-[2alpha,3beta(Z)]]- (9CI)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Oxiranecarboxaldehyde, 3-methyl-3-(3-pentenyl)-, [2R-[2alpha,3beta(Z)]]- (9CI)

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of Oxiranecarboxaldehyde, 3-methyl-3-(3-pentenyl)-, [2R-[2alpha,3beta(Z)]]- (9CI)

There total 6 articles about Oxiranecarboxaldehyde, 3-methyl-3-(3-pentenyl)-, [2R-[2alpha,3beta(Z)]]- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (2R,3S) 2,3-epoxy-1-hydroxy-3-methyl-6-octene

: 176695-89-9,176778-27-1
(2R,3S)-3-Methyl-3-((Z)-pent-3-enyl)-oxirane-2-carbaldehyde

: 176695-89-9,176778-27-1
(2R,3S)-3-Methyl-3-((E)-pent-3-enyl)-oxirane-2-carbaldehyde

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -60 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1016/0040-4020(96)00167-6

Reference yield:

: (2R,3S) 2,3-epoxy-1-hydroxy-3-methyl-6-octene

: 176695-89-9,176778-27-1
(2R,3S)-3-Methyl-3-((Z)-pent-3-enyl)-oxirane-2-carbaldehyde

: 176695-89-9,176778-27-1
(2R,3S)-3-Methyl-3-((E)-pent-3-enyl)-oxirane-2-carbaldehyde

Guidance literature:: With oxalyl dichloride; dimethyl sulfoxide; In dichloromethane; at -60 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1016/0040-4020(96)00167-6

Reference yield:

: 82188-73-6
(2S,3S)-2,3-epoxygeraniol

: 176695-89-9,176778-27-1
(2R,3S)-3-Methyl-3-((Z)-pent-3-enyl)-oxirane-2-carbaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / O₃, DMS / CH₂Cl₂ / -78 - 20 °C

2: 17 percent / 1.) BuLi / tetrahydrofuran / 0 °C

3: oxalyl chloride, DMSO / CH₂Cl₂ / -60 °C

With n-butyllithium; oxalyl dichloride; 2,3-dimercapto-succinic acid; ozone; dimethyl sulfoxide; In tetrahydrofuran; dichloromethane;
DOI:10.1016/0040-4020(96)00167-6