Technology Process of C24H29NO8S
There total 9 articles about C24H29NO8S which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2
2.1: hydrogen / 45004.5 Torr
3.1: pyridine
4.1: lithium hexamethyldisilazane
5.1: acetic acid / water / 0.6 h / 50 °C
5.2: -78 °C
5.3: Cooling with ice
6.1: silver(l) oxide / acetonitrile / 12 h / Reflux
7.1: sodium hydroxide / tetrahydrofuran; water / 0.5 h / 18 °C
8.1: oxalyl dichloride / dichloromethane / 0.25 h / -78 °C / Inert atmosphere
8.2: 1 h / -78 °C / Inert atmosphere
8.3: -78 - 0 °C / Inert atmosphere
With
pyridine; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; oxalyl dichloride; hydrogen; acetic acid; sodium hydroxide; silver(l) oxide; lithium hexamethyldisilazane;
In
tetrahydrofuran; dichloromethane; water; acetonitrile;
1.1: Suzuki-Miyaura cross-coupling / 6.1: Irvine-Purdie methylation / 8.1: Swern oxidation / 8.2: Swern oxidation / 8.3: Swern oxidation;
DOI:10.1016/j.tetlet.2011.06.050
- Guidance literature:
-
Multi-step reaction with 9 steps
1.1: carbon disulfide; sodium hydride
2.1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2
3.1: hydrogen / 45004.5 Torr
4.1: pyridine
5.1: lithium hexamethyldisilazane
6.1: acetic acid / water / 0.6 h / 50 °C
6.2: -78 °C
6.3: Cooling with ice
7.1: silver(l) oxide / acetonitrile / 12 h / Reflux
8.1: sodium hydroxide / tetrahydrofuran; water / 0.5 h / 18 °C
9.1: oxalyl dichloride / dichloromethane / 0.25 h / -78 °C / Inert atmosphere
9.2: 1 h / -78 °C / Inert atmosphere
9.3: -78 - 0 °C / Inert atmosphere
With
pyridine; carbon disulfide; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; oxalyl dichloride; hydrogen; sodium hydride; acetic acid; sodium hydroxide; silver(l) oxide; lithium hexamethyldisilazane;
In
tetrahydrofuran; dichloromethane; water; acetonitrile;
1.1: Barton-McCombie deoxygenation / 1.2: Barton-McCombie deoxygenation / 1.3: Barton-McCombie deoxygenation / 2.1: Suzuki-Miyaura cross-coupling / 7.1: Irvine-Purdie methylation / 9.1: Swern oxidation / 9.2: Swern oxidation / 9.3: Swern oxidation;
DOI:10.1016/j.tetlet.2011.06.050
- Guidance literature:
-
Multi-step reaction with 8 steps
1.1: dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2
2.1: hydrogen / 45004.5 Torr
3.1: pyridine
4.1: lithium hexamethyldisilazane
5.1: acetic acid / water / 0.6 h / 50 °C
5.2: -78 °C
5.3: Cooling with ice
6.1: silver(l) oxide / acetonitrile / 12 h / Reflux
7.1: sodium hydroxide / tetrahydrofuran; water / 0.5 h / 18 °C
8.1: oxalyl dichloride / dichloromethane / 0.25 h / -78 °C / Inert atmosphere
8.2: 1 h / -78 °C / Inert atmosphere
8.3: -78 - 0 °C / Inert atmosphere
With
pyridine; dichloro(1,1'-bis(diphenylphosphanyl)ferrocene)palladium(II)*CH2Cl2; oxalyl dichloride; hydrogen; acetic acid; sodium hydroxide; silver(l) oxide; lithium hexamethyldisilazane;
In
tetrahydrofuran; dichloromethane; water; acetonitrile;
1.1: Suzuki-Miyaura cross-coupling / 6.1: Irvine-Purdie methylation / 8.1: Swern oxidation / 8.2: Swern oxidation / 8.3: Swern oxidation;
DOI:10.1016/j.tetlet.2011.06.050