(2R,4aR,6S,7R,8R,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-ol

Base Information

Chemical Name:(2R,4aR,6S,7R,8R,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-ol
CAS No.:186820-62-2
Molecular Formula:C₄₉H₅₄O₁₀
Molecular Weight:802.962
Hs Code.:

(2R,4aR,6S,7R,8R,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-ol

Synonyms:(2R,4aR,6S,7R,8R,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-ol

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Chemical Property of (2R,4aR,6S,7R,8R,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-ol

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Technology Process of (2R,4aR,6S,7R,8R,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-ol

There total 2 articles about (2R,4aR,6S,7R,8R,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 19488-49-4
methyl 2,3,6-tri-O-benzyl-β-D-glucopyranoside

: 142789-96-6
1,2-O-anhydro-3-O-benzyl-4,6-O-benzylidene-5a-carba-β-D-mannopyranose

: 186820-62-2
(2R,4aR,6S,7R,8R,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-ol

Guidance literature:: With 15-crown-5; sodium hydride; In N,N-dimethyl-formamide; at 70 ℃; for 3h;
DOI:10.1016/j.carres.2009.09.008

Reference yield:

: 186820-64-4
(2R,4aR,6S,8S,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-one

: C₄₉H₅₄O₁₀

: 186820-62-2
(2R,4aR,6S,7R,8R,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-ol

Guidance literature:: With sodium tetrahydroborate; In methanol; dichloromethane; at 0 ℃;
DOI:10.1016/j.carres.2009.09.008

Reference yield: 74.0%

: 186820-62-2
(2R,4aR,6S,7R,8R,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-ol

: 186820-64-4
(2R,4aR,6S,8S,8aR)-8-Benzyloxy-6-((2R,3R,4S,5R,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methoxy-tetrahydro-pyran-3-yloxy)-2-phenyl-hexahydro-benzo[1,3]dioxin-7-one

Guidance literature:: With acetic anhydride; dimethyl sulfoxide; for 4h; Ambient temperature;
DOI:10.1002/(SICI)1099-0690(199806)1998:6<1099::AID-EJOC1099<3.0.CO;2-R