tert-butyl (1S,2S,3S,4R,5S)-2,3,4-trihydroxy-5-methylcyclohexyl carbonate

Base Information

• Chemical Name: tert-butyl (1S,2S,3S,4R,5S)-2,3,4-trihydroxy-5-methylcyclohexyl carbonate
• CAS No.: 1092513-29-5
• Molecular Formula: C₁₂H₂₂O₆
• Molecular Weight: 262.303
• Mol file: 1092513-29-5.mol

Synonyms:tert-butyl (1S,2S,3S,4R,5S)-2,3,4-trihydroxy-5-methylcyclohexyl carbonate

Chemical Property of tert-butyl (1S,2S,3S,4R,5S)-2,3,4-trihydroxy-5-methylcyclohexyl carbonate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of tert-butyl (1S,2S,3S,4R,5S)-2,3,4-trihydroxy-5-methylcyclohexyl carbonate

There total 1 articles about tert-butyl (1S,2S,3S,4R,5S)-2,3,4-trihydroxy-5-methylcyclohexyl carbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

tert-butyl (1S,4R,5S)-4-hydroxy-5-methylcyclohex-2-enyl carbonate (1092513-27-3) → tert-butyl (1S,2S,3S,4R,5S)-2,3,4-trihydroxy-5-methylcyclohexyl carbonate (1092513-29-5)

Guidance literature:

With osmium(VIII) oxide; 4-methylmorpholine N-oxide; In water; acetone; tert-butyl alcohol; at 0 ℃;

DOI:10.1055/s-2008-1067262

Reference yield: 83.0%

tert-butyl (1S,2S,3S,4R,5S)-2,3,4-trihydroxy-5-methylcyclohexyl carbonate (1092513-29-5) → (1S,2R,3S,4R,5S)-5-methylcyclohexane-1,2,3,4-tetraol (1092513-30-8)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 - 20 ℃;

DOI:10.1055/s-2008-1067262

upstream raw materials:

tert-butyl (1S,4R,5S)-4-hydroxy-5-methylcyclohex-2-enyl carbonate

Downstream raw materials:

(1S,2R,3S,4R,5S)-5-methylcyclohexane-1,2,3,4-tetraol