diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)thio]}dipropanoate

Base Information

• Chemical Name: diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)thio]}dipropanoate
• CAS No.: 1015689-80-1
• Molecular Formula: C₂₆H₄₀N₂O₆S₂
• Molecular Weight: 540.745
• Mol file: 1015689-80-1.mol

Synonyms:diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)thio]}dipropanoate

Chemical Property of diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)thio]}dipropanoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)thio]}dipropanoate

There total 1 articles about diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)thio]}dipropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

N,M'-bis(3-methyl-3-sulfanylbutyryl)-o-phenylenediamine + ethyl acrylate (140-88-5,9003-32-1) → diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)thio]}dipropanoate (1015689-80-1)

Guidance literature:

With sodium methylate; In methanol; ethanol; at 20 ℃; for 5h;

DOI:10.1016/j.tet.2007.12.023

Reference yield: 99.0%

diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)thio]}dipropanoate (1015689-80-1) → diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)sulfonyl]}dipropanoate (1015689-87-8)

Guidance literature:

With 3,3-dimethyldioxirane; In acetone; at 0 ℃; for 1h;

DOI:10.1016/j.tet.2007.12.023

Reference yield: 97.0%

diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)thio]}dipropanoate (1015689-80-1) → diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)sulfinyl]}dipropanoate (1015689-83-4)

Guidance literature:

With (3S)-3-tert-butyl-3-methyl-2-(phenylsulfonyl)oxaziridine; In tetrahydrofuran; at 20 ℃; for 12h;

DOI:10.1016/j.tet.2007.12.023

upstream raw materials:

ethyl acrylate

Downstream raw materials:

diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)sulfonyl]}dipropanoate

ethyl 3-[(3-{[2-({3-[(3-ethoxy-3-oxopropyl)sulfinyl]-3-methylbutanoyl}amino)phenyl]amino}-1,1-dimethyl-3-oxopropyl)thio]propanoate

diethyl 3,3'-{1,2-phenylenebis[imino(2-methyl-4-oxobutane-4,2-diyl)sulfinyl]}dipropanoate

ethyl 3-[(3-{[2-({3-[(3-ethoxy-3-oxopropyl)sulfinyl]-3-methylbutanoyl}amino)phenyl]amino}-1,1-dimethyl-3-oxopropyl)sulfonyl]propanoate